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Avila DV, Ingold KU, Lusztyk J, et al. Absolute Rate Constants for Radical Additions to Alkenes in Solution. The Synergistic Effect of Perfluorination on the Reactivities of n-Alkyl Radicals. J Org Chem. 1996;61(6):2027-2030doi: 10.1021/jo951782v.
Avila, D. V., Ingold, K. U., Lusztyk, J., Dolbier, W. R., & Pan, H. Q. (1996). Absolute Rate Constants for Radical Additions to Alkenes in Solution. The Synergistic Effect of Perfluorination on the Reactivities of n-Alkyl Radicals. The Journal of organic chemistry, 61(6), 2027-2030. https://doi.org/10.1021/jo951782v
Avila, David V, et al. "Absolute Rate Constants for Radical Additions to Alkenes in Solution. The Synergistic Effect of Perfluorination on the Reactivities of n-Alkyl Radicals." The Journal of organic chemistry vol. 61,6 (1996): 2027-2030. doi: https://doi.org/10.1021/jo951782v
Avila DV, Ingold KU, Lusztyk J, Dolbier WR, Pan HQ. Absolute Rate Constants for Radical Additions to Alkenes in Solution. The Synergistic Effect of Perfluorination on the Reactivities of n-Alkyl Radicals. J Org Chem. 1996 Mar 22;61(6):2027-2030. doi: 10.1021/jo951782v. PMID: 28616983.
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J Org Chem. 1996 Mar 22;61(6):2027-2030. doi: 10.1021/jo951782v.

Absolute Rate Constants for Radical Additions to Alkenes in Solution. The Synergistic Effect of Perfluorination on the Reactivities of n-Alkyl Radicals.

The Journal of organic chemistry

David V Avila, K U Ingold, J Lusztyk, W R Dolbier, H-Q Pan

Affiliations

  1. Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, Ontario, Canada K1A OR6, and the Department of Chemistry, University of Florida, Gainesville, Florida 32611.

PMID: 28616983 DOI: 10.1021/jo951782v

Abstract

Laser flash photolysis has been used to determine the absolute rate constants for addition of several partially fluorinated n-alkyl radicals to three styrenes at 25 °C in Freon 113. Fluorination at the γ-position (RCF

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