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Chem Sci. 2015 Dec 01;6(12):7179-7184. doi: 10.1039/c5sc02252e. Epub 2015 Sep 29.

The approach to 4d/4f-polyphosphides.

Chemical science

Nicholas Arleth, Michael T Gamer, Ralf Köppe, Nikolay A Pushkarevsky, Sergey N Konchenko, Martin Fleischmann, Michael Bodensteiner, Manfred Scheer, Peter W Roesky

Affiliations

  1. Institute of Inorganic Chemistry , Karlsruhe Institute of Technology , Engesserstrasse 15 , 76131 Karlsruhe , Germany . Email: [email protected].
  2. Nikolaev Institute of Inorganic Chemistry SB RAS , Novosibirsk State University , Prosp. Lavrentieva 3, Pirogova str. 2 , 630090 Novosibirsk , Russia . Email: [email protected].
  3. Institute of Inorganic Chemistry , University of Regensburg , 93040 Regensburg , Germany . Email: [email protected].

PMID: 28757983 PMCID: PMC5512014 DOI: 10.1039/c5sc02252e

Abstract

The first 4d/4f polyphosphides were obtained by reaction of the divalent metallocenes [Cp*

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