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Angew Chem Int Ed Engl. 2017 Oct 23;56(44):13713-13716. doi: 10.1002/anie.201707508. Epub 2017 Sep 22.

Spin Changes Accompany Ultrafast Structural Interconversion in the Ground State of a Cobalt Nitrosyl Complex.

Angewandte Chemie (International ed. in English)

Hugo J B Marroux, Basile F E Curchod, Charly A Faradji, Timothy A Shuttleworth, Hazel A Sparkes, Paul G Pringle, Andrew J Orr-Ewing

Affiliations

  1. School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK.

PMID: 28869320 DOI: 10.1002/anie.201707508

Abstract

Ultrafast, reversible intersystem crossing (ISC) is reported under ambient conditions for the electronic ground state of the pentacoordinate cobalt nitrosyl complexes, [CoX

© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: 2D infrared spectroscopy; electron spin; intersystem crossing; nitrosyl ligand; ultrafast dynamics

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