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Jacquet J, Cheaib K, Ren Y, et al. Circumventing Intrinsic Metal Reactivity: Radical Generation with Redox-Active Ligands. Chemistry. 2017;23(60):15030-15034doi: 10.1002/chem.201704049.
Jacquet, J., Cheaib, K., Ren, Y., Vezin, H., Orio, M., Blanchard, S., Fensterbank, L., & Desage-El Murr, M. (2017). Circumventing Intrinsic Metal Reactivity: Radical Generation with Redox-Active Ligands. Chemistry (Weinheim an der Bergstrasse, Germany), 23(60), 15030-15034. https://doi.org/10.1002/chem.201704049
Jacquet, Jérémy, et al. "Circumventing Intrinsic Metal Reactivity: Radical Generation with Redox-Active Ligands." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 23,60 (2017): 15030-15034. doi: https://doi.org/10.1002/chem.201704049
Jacquet J, Cheaib K, Ren Y, Vezin H, Orio M, Blanchard S, Fensterbank L, Desage-El Murr M. Circumventing Intrinsic Metal Reactivity: Radical Generation with Redox-Active Ligands. Chemistry. 2017 Oct 26;23(60):15030-15034. doi: 10.1002/chem.201704049. Epub 2017 Oct 09. PMID: 28873243.
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Chemistry. 2017 Oct 26;23(60):15030-15034. doi: 10.1002/chem.201704049. Epub 2017 Oct 09.

Circumventing Intrinsic Metal Reactivity: Radical Generation with Redox-Active Ligands.

Chemistry (Weinheim an der Bergstrasse, Germany)

Jérémy Jacquet, Khaled Cheaib, Yufeng Ren, Hervé Vezin, Maylis Orio, Sébastien Blanchard, Louis Fensterbank, Marine Desage-El Murr

Affiliations

  1. Sorbonne Universités, UPMC, Université Paris 06, UMR CNRS 8232, Institut Parisien de Chimie Moléculaire, France.
  2. Laboratoire de Spectrochimie Infrarouge et Raman, Université des Sciences et Technologies de Lille, UMR CNRS 8516, 59655 Villeneuve d'Ascq Cedex, France.
  3. Aix Marseille Université, CNRS, Centrale Marseille iSm2 UMR 7313, 13397, Marseille cedex 20, France.
  4. Institut de Chimie, Université de Strasbourg, 1 rue Blaise Pascal, 67000, Strasbourg, France.

PMID: 28873243 DOI: 10.1002/chem.201704049

Abstract

Nickel complexes have gained sustained attention as efficient catalysts in cross-coupling reactions and co-catalysts in dual systems due to their ability to react with radical species. Central to this reactivity is nickel's propensity to shuttle through several accessible redox states from Ni

© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: CF3. radicals; nickel; redox-active ligand; single electron transfer

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