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Phys Chem Chem Phys. 2017 Sep 20;19(36):24985-24990. doi: 10.1039/c7cp03924g.

The role of amino acid side chains in stabilizing dipeptides: the laser ablation Fourier transform microwave spectrum of Ac-Val-NH.

Physical chemistry chemical physics : PCCP

I León, E R Alonso, S Mata, C Cabezas, M A Rodríguez, J-U Grabow, J L Alonso

Affiliations

  1. Grupo de Espectrocopía Molecular (GEM), Edificio Quifima, Laboratorios de Espectroscopia y Bioespectroscopia, Unidad Asociada CSIC, Parque Científico UVa, Universidad de Valladolid, 47011, Valladolid, Spain. [email protected].

PMID: 28875198 DOI: 10.1039/c7cp03924g

Abstract

The steric effects imposed by the isopropyl group of valine in the conformational stabilization of the capped dipeptide N-acetyl-l-valinamide (Ac-Val-NH

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