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J Am Chem Soc. 2017 Sep 27;139(38):13260-13263. doi: 10.1021/jacs.7b06197. Epub 2017 Sep 13.

Single-Ion Li.

Journal of the American Chemical Society

Sarah S Park, Yuri Tulchinsky, Mircea Dincă

Affiliations

  1. Department of Chemistry, Massachusetts Institute of Technology , 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.

PMID: 28880535 DOI: 10.1021/jacs.7b06197

Abstract

A novel Cu(II)-azolate metal-organic framework (MOF) with tubular pores undergoes a reversible single crystal to single crystal transition between neutral and anionic phases upon reaction with stoichiometric amounts of halide or pseudohalide salts. The stoichiometric transformation between the two phases allows loading of record amounts of charge-balancing Li

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