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J Phys Chem Lett. 2017 Sep 21;8(18):4492-4497. doi: 10.1021/acs.jpclett.7b01942. Epub 2017 Sep 06.

Water Librations in the Hydration Shell of Phospholipids.

The journal of physical chemistry letters

Giulia Folpini, Torsten Siebert, Michael Woerner, Stephane Abel, Damien Laage, Thomas Elsaesser

Affiliations

  1. Max-Born-Institut für Nichtlineare Optik und Kurzzeitspektroskopie , D-12489 Berlin, Germany.
  2. Institut de Biologie Intégrative de la Cellule (I2BC), Institut Frédéric Joliot, CEA, CNRS, Univ Paris-Sud Université Paris-Saclay, 91405 Gif-Sur-Yvette Cedex, France.
  3. École Normale Supérieure, PSL Research University, UPMC Univ Paris 06, CNRS, Département de Chimie, PASTEUR, 24 rue Lhomond, 75005 Paris, France.
  4. Sorbonne Universités, UPMC Univ Paris 06, ENS, CNRS, PASTEUR, 75005 Paris, France.

PMID: 28858510 DOI: 10.1021/acs.jpclett.7b01942

Abstract

The hydrophilic phosphate moiety in the headgroup of phospholipids forms strong hydrogen bonds with water molecules in the first hydration layer. Time-domain terahertz spectroscopy in a range from 100 to 1000 cm

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