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Adv Mater. 2017 Oct;29(40). doi: 10.1002/adma.201703399. Epub 2017 Aug 31.

Twinned Growth of Metal-Free, Triazine-Based Photocatalyst Films as Mixed-Dimensional (2D/3D) van der Waals Heterostructures.

Advanced materials (Deerfield Beach, Fla.)

Dana Schwarz, Yu Noda, Jan Klouda, Karolina Schwarzová-Pecková, Ján Tarábek, Jiří Rybáček, Jiří Janoušek, Frank Simon, Maksym V Opanasenko, Jiří Čejka, Amitava Acharjya, Johannes Schmidt, Sören Selve, Valentin Reiter-Scherer, Nikolai Severin, Jürgen P Rabe, Petra Ecorchard, Junjie He, Miroslav Polozij, Petr Nachtigall, Michael J Bojdys

Affiliations

  1. Faculty of Science, Department of Organic Chemistry, Charles University, Hlavova 8, 128 43, Prague 2, Czech Republic.
  2. Institute of Organic Chemistry and Biochemistry of the CAS, Flemingovo nám. 2, 166 10, Prague 6, Czech Republic.
  3. Faculty of Science, Department of Analytical Chemistry, Charles University, Hlavova 8, 128 43, Prague 2, Czech Republic.
  4. Faculty of Chemical Engineering, Department of Analytical Chemistry, University of Chemistry and Technology Prague, Technická 3, 160 00, Prague 6, Czech Republic.
  5. Leibniz Institute of Polymer Research Dresden, Hohe Str. 6, 01069, Dresden, Germany.
  6. J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, v.v.i., Dolejškova 2155/3, 182 00, Prague 8, Czech Republic.
  7. Technische Universität Berlin, Institute of Chemistry, Hardenbergstr. 40, 10623, Berlin, Germany.
  8. Humboldt-Universität zu Berlin, Department of Physics, Physics of Macromolecules, Newtonstr. 15, 12489, Berlin, Germany.
  9. Materials Chemistry Department, Institute of Inorganic Chemistry AS CR, v.v.i., 250 68, ?ež, Czech Republic.
  10. Faculty of Science, Department of Physical and Macromolecular Chemistry, Charles University, Hlavova 8, 128 43, Prague 2, Czech Republic.

PMID: 28859235 DOI: 10.1002/adma.201703399

Abstract

Design and synthesis of ordered, metal-free layered materials is intrinsically difficult due to the limitations of vapor deposition processes that are used in their making. Mixed-dimensional (2D/3D) metal-free van der Waals (vdW) heterostructures based on triazine (C

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: 2D materials; conjugated microporous polymers; donor-acceptor; membranes; triazine

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