Display options
Cite
Imaoka T, Akanuma Y, Haruta N, et al. Platinum clusters with precise numbers of atoms for preparative-scale catalysis. Nat Commun. 2017;8(1):688doi: 10.1038/s41467-017-00800-4.
Imaoka, T., Akanuma, Y., Haruta, N., Tsuchiya, S., Ishihara, K., Okayasu, T., Chun, W. J., Takahashi, M., & Yamamoto, K. (2017). Platinum clusters with precise numbers of atoms for preparative-scale catalysis. Nature communications, 8(1), 688. https://doi.org/10.1038/s41467-017-00800-4
Imaoka, Takane, et al. "Platinum clusters with precise numbers of atoms for preparative-scale catalysis." Nature communications vol. 8,1 (2017): 688. doi: https://doi.org/10.1038/s41467-017-00800-4
Imaoka T, Akanuma Y, Haruta N, Tsuchiya S, Ishihara K, Okayasu T, Chun WJ, Takahashi M, Yamamoto K. Platinum clusters with precise numbers of atoms for preparative-scale catalysis. Nat Commun. 2017 Sep 25;8(1):688. doi: 10.1038/s41467-017-00800-4. PMID: 28947792; PMCID: PMC5613004.
Copy Download .nbib Format: NLM
Share it on

Nat Commun. 2017 Sep 25;8(1):688. doi: 10.1038/s41467-017-00800-4.

Platinum clusters with precise numbers of atoms for preparative-scale catalysis.

Nature communications

Takane Imaoka, Yuki Akanuma, Naoki Haruta, Shogo Tsuchiya, Kentaro Ishihara, Takeshi Okayasu, Wang-Jae Chun, Masaki Takahashi, Kimihisa Yamamoto

Affiliations

  1. Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, Yokohama, 226-8503, Japan. [email protected].
  2. ERATO-JST, Saitama, Kawaguchi, 332-0012, Japan. [email protected].
  3. PRESTO-JST, Saitama, Kawaguchi, 332-0012, Japan. [email protected].
  4. Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, Yokohama, 226-8503, Japan.
  5. ERATO-JST, Saitama, Kawaguchi, 332-0012, Japan.
  6. Graduate School of Arts and Sciences, International Christian University, Tokyo, 181-8585, Japan.
  7. Department of Applied Chemistry, Faculty of Engineering, Yamanashi University, Kofu, 400-8501, Japan.
  8. Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, Yokohama, 226-8503, Japan. [email protected].
  9. ERATO-JST, Saitama, Kawaguchi, 332-0012, Japan. [email protected].

PMID: 28947792 PMCID: PMC5613004 DOI: 10.1038/s41467-017-00800-4

Abstract

Subnanometer noble metal clusters have enormous potential, mainly for catalytic applications. Because a difference of only one atom may cause significant changes in their reactivity, a preparation method with atomic-level precision is essential. Although such a precision with enough scalability has been achieved by gas-phase synthesis, large-scale preparation is still at the frontier, hampering practical applications. We now show the atom-precise and fully scalable synthesis of platinum clusters on a milligram scale from tiara-like platinum complexes with various ring numbers (n = 5-13). Low-temperature calcination of the complexes on a carbon support under hydrogen stream affords monodispersed platinum clusters, whose atomicity is equivalent to that of the precursor complex. One of the clusters (Pt

References

  1. J Chem Phys. 2005 Sep 22;123(12):124709 - PubMed
  2. Science. 2009 Jan 23;323(5913):492-5 - PubMed
  3. Angew Chem Int Ed Engl. 2010 Jun 7;49(25):4209-12 - PubMed
  4. Science. 2010 Apr 9;328(5975):224-8 - PubMed
  5. J Am Chem Soc. 2013 Feb 27;135(8):3073-86 - PubMed
  6. Dalton Trans. 2013 Sep 21;42(35):12662-6 - PubMed
  7. Acc Chem Res. 2014 Apr 15;47(4):1054-66 - PubMed
  8. Nanoscale. 2015 Dec 14;7(46):19448-52 - PubMed
  9. J Am Chem Soc. 2013 Sep 4;135(35):13089-95 - PubMed
  10. J Am Chem Soc. 2011 Mar 16;133(10):3582-91 - PubMed
  11. Nano Lett. 2011 Sep 14;11(9):3714-9 - PubMed
  12. Nat Chem. 2009 Aug;1(5):397-402 - PubMed
  13. Nature. 2008 Aug 21;454(7207):981-3 - PubMed
  14. Chem Soc Rev. 2014 Dec 21;43(24):8226-39 - PubMed
  15. Acc Chem Res. 2014 Mar 18;47(3):816-24 - PubMed
  16. Inorg Chem. 2013 Aug 5;52(15):9094-101 - PubMed
  17. Nature. 2012 Jun 06;486(7401):43-51 - PubMed
  18. Phys Rev Lett. 1990 Feb 12;64(7):780-783 - PubMed
  19. Angew Chem Int Ed Engl. 2006 Jul 3;45(27):4416-39 - PubMed
  20. Sci Rep. 2015 Nov 16;5:16628 - PubMed
  21. Nat Commun. 2016 Jan 28;7:10389 - PubMed
  22. Angew Chem Int Ed Engl. 2014 Aug 4;53(32):8316-9 - PubMed
  23. Science. 2012 May 18;336(6083):893-7 - PubMed
  24. Chem Commun (Camb). 2006 Jun 28;(24):2581-2 - PubMed
  25. Inorg Chem. 2014 Apr 7;53(7):3558-67 - PubMed
  26. Angew Chem Int Ed Engl. 2006 Jun 2;45(23):3768-72 - PubMed
  27. J Phys Chem A. 2014 Nov 13;118(45):10813-21 - PubMed
  28. Nat Mater. 2009 Mar;8(3):213-6 - PubMed
  29. Science. 2007 May 4;316(5825):732-5 - PubMed
  30. Dalton Trans. 2013 Dec 7;42(45):15919-21 - PubMed
  31. J Phys Chem A. 2005 Dec 29;109(51):11647-9 - PubMed
  32. Chem Rev. 2016 Feb 24;116(4):2705-74 - PubMed
  33. Dalton Trans. 2012 Jul 21;41(27):8472-6 - PubMed
  34. Nat Nanotechnol. 2015 Jul;10(7):577-88 - PubMed
  35. Adv Sci (Weinh). 2015 Jun 10;2(7):1500085 - PubMed
  36. Science. 2009 Nov 6;326(5954):826-9 - PubMed

Publication Types