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Daud NMAN, Bakis E, Hallett JP, et al. Evidence for the spontaneous formation of N-heterocyclic carbenes in imidazolium based ionic liquids. Chem Commun (Camb). 2017;53(81):11154-11156doi: 10.1039/c7cc06112a.
Daud, N. M. A. N., Bakis, E., Hallett, J. P., Weber, C. C., & Welton, T. (2017). Evidence for the spontaneous formation of N-heterocyclic carbenes in imidazolium based ionic liquids. Chemical communications (Cambridge, England), 53(81), 11154-11156. https://doi.org/10.1039/c7cc06112a
Daud, N M A N, et al. "Evidence for the spontaneous formation of N-heterocyclic carbenes in imidazolium based ionic liquids." Chemical communications (Cambridge, England) vol. 53,81 (2017): 11154-11156. doi: https://doi.org/10.1039/c7cc06112a
Daud NMAN, Bakis E, Hallett JP, Weber CC, Welton T. Evidence for the spontaneous formation of N-heterocyclic carbenes in imidazolium based ionic liquids. Chem Commun (Camb). 2017 Oct 18;53(81):11154-11156. doi: 10.1039/c7cc06112a. Epub 2017 Sep 11. PMID: 28890962.
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Chem Commun (Camb). 2017 Oct 18;53(81):11154-11156. doi: 10.1039/c7cc06112a. Epub 2017 Sep 11.

Evidence for the spontaneous formation of N-heterocyclic carbenes in imidazolium based ionic liquids.

Chemical communications (Cambridge, England)

N M A N Daud, E Bakis, J P Hallett, C C Weber, T Welton

Affiliations

  1. Department of Chemistry, Imperial College London, London, SW7 2AZ, UK. [email protected].

PMID: 28890962 DOI: 10.1039/c7cc06112a

Abstract

We present a study of the reactions of aldehydes in ionic liquids which gives evidence for the spontaneous formation of N-heterocyclic carbenes in ionic liquids based on 1,3-dialkyl substituted imidazolium cations from the lack of a deuterium isotope effect on the reaction of these ionic liquids with aldehydes.

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