Display options
Share it on

Nanoscale. 2017 Sep 28;9(37):13990-13997. doi: 10.1039/c7nr04527a.

Facile fabrication of mesoporous silica micro-jets with multi-functionalities.

Nanoscale

D Vilela, A C Hortelao, R Balderas-Xicohténcatl, M Hirscher, K Hahn, X Ma, S Sánchez

Affiliations

  1. Max Planck Institute for Intelligent Systems, Heisenbergstr. 3, 70569 Stuttgart, Germany. [email protected] [email protected].

PMID: 28891580 PMCID: PMC5708346 DOI: 10.1039/c7nr04527a

Abstract

Self-propelled micro/nano-devices have been proved as powerful tools in various applications given their capability of both autonomous motion and on-demand task fulfilment. Tubular micro-jets stand out as an important member in the family of self-propelled micro/nano-devices and are widely explored with respect to their fabrication and functionalization. A few methods are currently available for the fabrication of tubular micro-jets, nevertheless there is still a demand to explore the fabrication of tubular micro-jets made of versatile materials and with the capability of multi-functionalization. Here, we present a facile strategy for the fabrication of mesoporous silica micro-jets (MSMJs) for tubular micromotors which can carry out multiple tasks depending on their functionalities. The synthesis of MSMJs does not require the use of any equipment, making it facile and cost-effective for future practical use. The MSMJs can be modified inside, outside or both with different kinds of metal nanoparticles, which provide these micromotors with a possibility of additional properties, such as the anti-bacterial effect by silver nanoparticles, or biochemical sensing based on surface enhanced Raman scattering (SERS) by gold nanoparticles. Because of the high porosity, high surface area and also the easy surface chemistry process, the MSMJs can be employed for the efficient removal of heavy metals in contaminated water, as well as for the controlled and active drug delivery, as two proof-of-concept examples of environmental and biomedical applications, respectively. Therefore, taking into account the new, simple and cheap method of fabrication, highly porous structure, and multiple functionalities, the mesoporous silica based micro-jets can serve as efficient tools for desired applications.

References

  1. ACS Nano. 2014 Apr 22;8(4):3170-80 - PubMed
  2. J Phys Chem Lett. 2012 Aug 16;3(16):2204-8 - PubMed
  3. ACS Nano. 2016 Feb 23;10 (2):2652-60 - PubMed
  4. Adv Mater. 2013 Jul 19;25(27):3715-21 - PubMed
  5. Chem Rev. 2015 Aug 26;115(16):8704-35 - PubMed
  6. ACS Nano. 2016 Oct 25;10 (10 ):9111-9122 - PubMed
  7. Anal Chem. 2011 Oct 15;83(20):7962-9 - PubMed
  8. Nanoscale. 2014 Jul 7;6(13):7175-82 - PubMed
  9. Nano Lett. 2015 Oct 14;15(10):7043-50 - PubMed
  10. Chemistry. 2013 Nov 11;19(46):15593-603 - PubMed
  11. ACS Nano. 2016 Mar 22;10(3):3597-605 - PubMed
  12. ACS Nano. 2013 Jan 22;7(1):818-24 - PubMed
  13. Nano Lett. 2015 Dec 9;15(12):8311-5 - PubMed
  14. J Am Chem Soc. 2016 Oct 26;138(42):13782-13785 - PubMed
  15. J Colloid Interface Sci. 2004 Jul 1;275(1):177-82 - PubMed
  16. Small. 2010 Aug 16;6(16):1794-805 - PubMed
  17. J Am Chem Soc. 2011 Aug 10;133(31):11862-4 - PubMed
  18. Nanoscale. 2014 Sep 21;6(18):10486-94 - PubMed
  19. Adv Mater. 2016 Feb 10;28(6):1060-72 - PubMed
  20. Nano Lett. 2016 Apr 13;16(4):2860-6 - PubMed
  21. Small. 2009 Jul;5(14):1688-92 - PubMed
  22. Angew Chem Int Ed Engl. 2013 Jul 1;52(27):7000-3 - PubMed
  23. ACS Nano. 2010 Dec 28;4(12):7451-8 - PubMed
  24. J Am Chem Soc. 2010 Jan 20;132(2):552-7 - PubMed
  25. Angew Chem Int Ed Engl. 2004 Nov 19;43(45):6042-108 - PubMed
  26. Chem Soc Rev. 2013 May 7;42(9):3862-75 - PubMed
  27. Angew Chem Int Ed Engl. 2015 Jan 26;54(5):1414-44 - PubMed
  28. Angew Chem Int Ed Engl. 2004 Nov 5;43(43):5812-5 - PubMed
  29. Biosens Bioelectron. 2015 May 15;67:42-8 - PubMed
  30. ACS Nano. 2014 Jun 24;8(6):6097-105 - PubMed
  31. Chem Rev. 2012 May 9;112(5):2739-79 - PubMed
  32. Biotechnol Adv. 2009 Jan-Feb;27(1):76-83 - PubMed
  33. J Am Chem Soc. 2009 Jul 15;131(27):9496-7 - PubMed
  34. Acc Chem Res. 2017 Jan 17;50(1):2-11 - PubMed
  35. ACS Nano. 2016 Jun 28;10(6):5619-34 - PubMed
  36. Nano Lett. 2012 Aug 8;12(8):4271-5 - PubMed
  37. ACS Nano. 2012 Feb 28;6(2):1751-6 - PubMed
  38. Nano Lett. 2011 May 11;11(5):2083-7 - PubMed
  39. ACS Nano. 2013 Nov 26;7(11):9611-20 - PubMed

Publication Types

Grant support