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Chen L, Sanchez DR, Zhang B, et al. "Cationic" Suzuki-Miyaura Coupling with Acutely Base-Sensitive Boronic Acids. J Am Chem Soc. 2017;139(36):12418-12421doi: 10.1021/jacs.7b07687.
Chen, L., Sanchez, D. R., Zhang, B., & Carrow, B. P. (2017). "Cationic" Suzuki-Miyaura Coupling with Acutely Base-Sensitive Boronic Acids. Journal of the American Chemical Society, 139(36), 12418-12421. https://doi.org/10.1021/jacs.7b07687
Chen, Liye, et al. ""Cationic" Suzuki-Miyaura Coupling with Acutely Base-Sensitive Boronic Acids." Journal of the American Chemical Society vol. 139,36 (2017): 12418-12421. doi: https://doi.org/10.1021/jacs.7b07687
Chen L, Sanchez DR, Zhang B, Carrow BP. "Cationic" Suzuki-Miyaura Coupling with Acutely Base-Sensitive Boronic Acids. J Am Chem Soc. 2017 Sep 13;139(36):12418-12421. doi: 10.1021/jacs.7b07687. Epub 2017 Sep 05. PMID: 28862445.
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J Am Chem Soc. 2017 Sep 13;139(36):12418-12421. doi: 10.1021/jacs.7b07687. Epub 2017 Sep 05.

"Cationic" Suzuki-Miyaura Coupling with Acutely Base-Sensitive Boronic Acids.

Journal of the American Chemical Society

Liye Chen, Daniel R Sanchez, Bufan Zhang, Brad P Carrow

Affiliations

  1. Department of Chemistry, Princeton University , Princeton, New Jersey 08544, United States.

PMID: 28862445 DOI: 10.1021/jacs.7b07687

Abstract

Fast, base-promoted protodeboronation of polyfluoroaryl and heteroaryl boronic acids complicates their use in Suzuki-Miyaura coupling (SMC) because a base is generally required for catalysis. We report a "cationic" SMC method using a PAd

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