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Kubicki DJ, Prochowicz D, Hofstetter A, et al. Phase Segregation in Cs-, Rb- and K-Doped Mixed-Cation (MA). J Am Chem Soc. 2017;139(40):14173-14180doi: 10.1021/jacs.7b07223.
Kubicki, D. J., Prochowicz, D., Hofstetter, A., Zakeeruddin, S. M., Grätzel, M., & Emsley, L. (2017). Phase Segregation in Cs-, Rb- and K-Doped Mixed-Cation (MA). Journal of the American Chemical Society, 139(40), 14173-14180. https://doi.org/10.1021/jacs.7b07223
Kubicki, Dominik J, et al. "Phase Segregation in Cs-, Rb- and K-Doped Mixed-Cation (MA)." Journal of the American Chemical Society vol. 139,40 (2017): 14173-14180. doi: https://doi.org/10.1021/jacs.7b07223
Kubicki DJ, Prochowicz D, Hofstetter A, Zakeeruddin SM, Grätzel M, Emsley L. Phase Segregation in Cs-, Rb- and K-Doped Mixed-Cation (MA). J Am Chem Soc. 2017 Oct 11;139(40):14173-14180. doi: 10.1021/jacs.7b07223. Epub 2017 Sep 27. PMID: 28892374; PMCID: PMC5719467.
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J Am Chem Soc. 2017 Oct 11;139(40):14173-14180. doi: 10.1021/jacs.7b07223. Epub 2017 Sep 27.

Phase Segregation in Cs-, Rb- and K-Doped Mixed-Cation (MA).

Journal of the American Chemical Society

Dominik J Kubicki, Daniel Prochowicz, Albert Hofstetter, Shaik M Zakeeruddin, Michael Grätzel, Lyndon Emsley

Affiliations

  1. Institute of Physical Chemistry, Polish Academy of Sciences , Kasprzaka 44/52, 01-224 Warsaw, Poland.

PMID: 28892374 PMCID: PMC5719467 DOI: 10.1021/jacs.7b07223

Abstract

Hybrid (organic-inorganic) multication lead halide perovskites hold promise for a new generation of easily processable solar cells. Best performing compositions to date are multiple-cation solid alloys of formamidinium (FA), methylammonium (MA), cesium, and rubidium lead halides which provide power conversion efficiencies up to around 22%. Here, we elucidate the atomic-level nature of Cs and Rb incorporation into the perovskite lattice of FA-based materials. We use

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