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Vandersteen AA, Howe GW, Sherwood Lollar B, et al. Carbon Kinetic Isotope Effects and the Mechanisms of Acid-Catalyzed Decarboxylation of 2,4-Dimethoxybenzoic Acid and CO. J Am Chem Soc. 2017;139(42):15049-15053doi: 10.1021/jacs.7b07504.
Vandersteen, A. A., Howe, G. W., Sherwood Lollar, B., & Kluger, R. (2017). Carbon Kinetic Isotope Effects and the Mechanisms of Acid-Catalyzed Decarboxylation of 2,4-Dimethoxybenzoic Acid and CO. Journal of the American Chemical Society, 139(42), 15049-15053. https://doi.org/10.1021/jacs.7b07504
Vandersteen, Adelle A, et al. "Carbon Kinetic Isotope Effects and the Mechanisms of Acid-Catalyzed Decarboxylation of 2,4-Dimethoxybenzoic Acid and CO." Journal of the American Chemical Society vol. 139,42 (2017): 15049-15053. doi: https://doi.org/10.1021/jacs.7b07504
Vandersteen AA, Howe GW, Sherwood Lollar B, Kluger R. Carbon Kinetic Isotope Effects and the Mechanisms of Acid-Catalyzed Decarboxylation of 2,4-Dimethoxybenzoic Acid and CO. J Am Chem Soc. 2017 Oct 25;139(42):15049-15053. doi: 10.1021/jacs.7b07504. Epub 2017 Oct 13. PMID: 28982238.
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J Am Chem Soc. 2017 Oct 25;139(42):15049-15053. doi: 10.1021/jacs.7b07504. Epub 2017 Oct 13.

Carbon Kinetic Isotope Effects and the Mechanisms of Acid-Catalyzed Decarboxylation of 2,4-Dimethoxybenzoic Acid and CO.

Journal of the American Chemical Society

Adelle A Vandersteen, Graeme W Howe, Barbara Sherwood Lollar, Ronald Kluger

Affiliations

  1. Davenport Chemical Research Laboratories, Department of Chemistry and The Stable Isotopes Laboratory, and ‡Department of Earth Sciences, University of Toronto , Toronto, Ontario M5S 3H6, Canada.

PMID: 28982238 DOI: 10.1021/jacs.7b07504

Abstract

The rate of decarboxylation of 2,4-dimethoxybenzoic acid (1) is accelerated in parallel to the extent that the carboxyl group acquires a second proton (1H

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