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Zhang X, da Silva I, Godfrey HGW, et al. Confinement of Iodine Molecules into Triple-Helical Chains within Robust Metal-Organic Frameworks. J Am Chem Soc. 2017;139(45):16289-16296doi: 10.1021/jacs.7b08748.
Zhang, X., da Silva, I., Godfrey, H. G. W., Callear, S. K., Sapchenko, S. A., Cheng, Y., Vitórica-Yrezábal, I., Frogley, M. D., Cinque, G., Tang, C. C., Giacobbe, C., Dejoie, C., Rudić, S., Ramirez-Cuesta, A. J., Denecke, M. A., Yang, S., & Schröder, M. (2017). Confinement of Iodine Molecules into Triple-Helical Chains within Robust Metal-Organic Frameworks. Journal of the American Chemical Society, 139(45), 16289-16296. https://doi.org/10.1021/jacs.7b08748
Zhang, Xinran, et al. "Confinement of Iodine Molecules into Triple-Helical Chains within Robust Metal-Organic Frameworks." Journal of the American Chemical Society vol. 139,45 (2017): 16289-16296. doi: https://doi.org/10.1021/jacs.7b08748
Zhang X, da Silva I, Godfrey HGW, Callear SK, Sapchenko SA, Cheng Y, Vitórica-Yrezábal I, Frogley MD, Cinque G, Tang CC, Giacobbe C, Dejoie C, Rudić S, Ramirez-Cuesta AJ, Denecke MA, Yang S, Schröder M. Confinement of Iodine Molecules into Triple-Helical Chains within Robust Metal-Organic Frameworks. J Am Chem Soc. 2017 Nov 15;139(45):16289-16296. doi: 10.1021/jacs.7b08748. Epub 2017 Nov 03. PMID: 29020767; PMCID: PMC5712866.
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J Am Chem Soc. 2017 Nov 15;139(45):16289-16296. doi: 10.1021/jacs.7b08748. Epub 2017 Nov 03.

Confinement of Iodine Molecules into Triple-Helical Chains within Robust Metal-Organic Frameworks.

Journal of the American Chemical Society

Xinran Zhang, Ivan da Silva, Harry G W Godfrey, Samantha K Callear, Sergey A Sapchenko, Yongqiang Cheng, Inigo Vitórica-Yrezábal, Mark D Frogley, Gianfelice Cinque, Chiu C Tang, Carlotta Giacobbe, Catherine Dejoie, Svemir Rudić, Anibal J Ramirez-Cuesta, Melissa A Denecke, Sihai Yang, Martin Schröder

Affiliations

  1. School of Chemistry, University of Manchester , Manchester M13 9PL, U.K.
  2. ISIS Facility, STFC Rutherford Appleton Laboratory , Chilton, Oxfordshire OX11 0QX, U.K.
  3. Nikolaev Institute of Inorganic Chemistry , Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia.
  4. The Chemical and Engineering Materials Division (CEMD), Neutron Sciences Directorate, Oak Ridge National Laboratory , Oak Ridge, Tennessee 37831, United States.
  5. Diamond Light Source , Harwell Science Campus, Oxfordshire OX11 0DE, U.K.
  6. European Synchrotron Radiation Facility , Grenoble 38043, France.

PMID: 29020767 PMCID: PMC5712866 DOI: 10.1021/jacs.7b08748

Abstract

During nuclear waste disposal process, radioactive iodine as a fission product can be released. The widespread implementation of sustainable nuclear energy thus requires the development of efficient iodine stores that have simultaneously high capacity, stability and more importantly, storage density (and hence minimized system volume). Here, we report high I

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