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DeVine JA, Weichman ML, Laws B, et al. Encoding of vinylidene isomerization in its anion photoelectron spectrum. Science. 2017;358(6361):336-339doi: 10.1126/science.aao1905.
DeVine, J. A., Weichman, M. L., Laws, B., Chang, J., Babin, M. C., Balerdi, G., Xie, C., Malbon, C. L., Lineberger, W. C., Yarkony, D. R., Field, R. W., Gibson, S. T., Ma, J., Guo, H., & Neumark, D. M. (2017). Encoding of vinylidene isomerization in its anion photoelectron spectrum. Science (New York, N.Y.), 358(6361), 336-339. https://doi.org/10.1126/science.aao1905
DeVine, Jessalyn A, et al. "Encoding of vinylidene isomerization in its anion photoelectron spectrum." Science (New York, N.Y.) vol. 358,6361 (2017): 336-339. doi: https://doi.org/10.1126/science.aao1905
DeVine JA, Weichman ML, Laws B, Chang J, Babin MC, Balerdi G, Xie C, Malbon CL, Lineberger WC, Yarkony DR, Field RW, Gibson ST, Ma J, Guo H, Neumark DM. Encoding of vinylidene isomerization in its anion photoelectron spectrum. Science. 2017 Oct 20;358(6361):336-339. doi: 10.1126/science.aao1905. PMID: 29051373.
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Science. 2017 Oct 20;358(6361):336-339. doi: 10.1126/science.aao1905.

Encoding of vinylidene isomerization in its anion photoelectron spectrum.

Science (New York, N.Y.)

Jessalyn A DeVine, Marissa L Weichman, Benjamin Laws, Jing Chang, Mark C Babin, Garikoitz Balerdi, Changjian Xie, Christopher L Malbon, W Carl Lineberger, David R Yarkony, Robert W Field, Stephen T Gibson, Jianyi Ma, Hua Guo, Daniel M Neumark

Affiliations

  1. Department of Chemistry, University of California, Berkeley, CA 94720, USA.
  2. Research School of Physics and Engineering, Australian National University, Canberra, ACT 2601, Australia.
  3. Institute of Atomic and Molecular Physics, Sichuan University, Chengdu, Sichuan 610067, China.
  4. Departmento de Química Física, Facultad de Ciencias Químicas, Universidad Complutense de Madrid (Unidad Asociada I+D+I CSIC), 28040 Madrid, Spain.
  5. Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, NM 87131, USA.
  6. Department of Chemistry, Johns Hopkins University, Baltimore, MD 21218, USA.
  7. JILA and Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309, USA.
  8. Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.
  9. Institute of Atomic and Molecular Physics, Sichuan University, Chengdu, Sichuan 610067, China. [email protected] [email protected].
  10. Department of Chemistry, University of California, Berkeley, CA 94720, USA. [email protected] [email protected].
  11. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.

PMID: 29051373 DOI: 10.1126/science.aao1905

Abstract

Vinylidene-acetylene isomerization is the prototypical example of a 1,2-hydrogen shift, one of the most important classes of isomerization reactions in organic chemistry. This reaction was investigated with quantum state specificity by high-resolution photoelectron spectroscopy of the vinylidene anions H

Copyright © 2017 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.

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