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J Colloid Interface Sci. 2018 Feb 01;511:92-100. doi: 10.1016/j.jcis.2017.09.115. Epub 2017 Sep 30.

A new microporous oxyfluorinated titanium(IV) phosphate as an efficient heterogeneous catalyst for the selective oxidation of cyclohexanone.

Journal of colloid and interface science

Piyali Bhanja, Sauvik Chatterjee, Astam K Patra, Asim Bhaumik

Affiliations

  1. Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur 700 032, India.
  2. Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur 700 032, India. Electronic address: [email protected].

PMID: 28988010 DOI: 10.1016/j.jcis.2017.09.115

Abstract

Designing a new porous nanomaterial for eco-friendly catalytic reactions is very challenging. Here, a new crystalline microporous oxyfluorinated titanium phosphate material (TIPO-1) has been synthesized under hydrothermal conditions in the absence of any structure directing agent. The triclinic crystalline phase with the unit cell parameters a=7.962Å, b=10.006Å, c=13.979Å, α=96.921°, β=95.851° and γ=93.760° has been indexed for TIPO-1 and it has been characterized through powder X-ray diffraction, nitrogen adsorption/desorption, XPS, FT-IR,

Copyright © 2017 Elsevier Inc. All rights reserved.

Keywords: Adipic acid synthesis; Liquid phase selective oxidation; Microporosity; Titanium phosphate; Triclinic phase

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