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J Chem Phys. 2017 Oct 21;147(15):154302. doi: 10.1063/1.4990514.

Effects of collision energy and vibrational excitation of CH.

The Journal of chemical physics

Andrea Cernuto, Allan Lopes, Claire Romanzin, Barbara Cunha de Miranda, Daniela Ascenzi, Paolo Tosi, Glauco Tonachini, Andrea Maranzana, Miroslav Polášek, Jan Žabka, Christian Alcaraz

Affiliations

  1. Department of Physics, University of Trento, Via Sommarive 14, Trento I-38123, Italy.
  2. Laboratoire de Chimie Physique, Bât. 350, UMR 8000, CNRS-Univ. Paris-Sud 11 and Paris Saclay, Centre Universitaire Paris-Sud, 91405 Orsay Cedex, France.
  3. Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin - BP 48, 91192 Gif-sur-Yvette, France.
  4. Department of Chemistry, University of Torino, Via Pietro Giuria, 7, Torino I-10125, Italy.
  5. J. Heyrovský Institute of Physical Chemistry of the Czech Academy of Sciences, Dolejškova 3, 182 23 Prague 8, Czech Republic.

PMID: 29055295 DOI: 10.1063/1.4990514

Abstract

The methyl carbocation is ubiquitous in gaseous environments, such as planetary ionospheres, cometary comae, and the interstellar medium, as well as combustion systems and plasma setups for technological applications. Here we report on a joint experimental and theoretical study on the mechanism of the reaction CH

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