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Jones MD, Brady L, McKeown P, et al. Metal influence on the iso- and hetero-selectivity of complexes of bipyrrolidine derived salan ligands for the polymerisation of . Chem Sci. 2015;6(8):5034-5039doi: 10.1039/c5sc01819f.
Jones, M. D., Brady, L., McKeown, P., Buchard, A., Schäfer, P. M., Thomas, L. H., Mahon, M. F., Woodman, T. J., & Lowe, J. P. (2015). Metal influence on the iso- and hetero-selectivity of complexes of bipyrrolidine derived salan ligands for the polymerisation of . Chemical science, 6(8), 5034-5039. https://doi.org/10.1039/c5sc01819f
Jones, Matthew D, et al. "Metal influence on the iso- and hetero-selectivity of complexes of bipyrrolidine derived salan ligands for the polymerisation of ." Chemical science vol. 6,8 (2015): 5034-5039. doi: https://doi.org/10.1039/c5sc01819f
Jones MD, Brady L, McKeown P, Buchard A, Schäfer PM, Thomas LH, Mahon MF, Woodman TJ, Lowe JP. Metal influence on the iso- and hetero-selectivity of complexes of bipyrrolidine derived salan ligands for the polymerisation of . Chem Sci. 2015 Aug 01;6(8):5034-5039. doi: 10.1039/c5sc01819f. Epub 2015 Jun 17. PMID: 29142728; PMCID: PMC5664169.
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Chem Sci. 2015 Aug 01;6(8):5034-5039. doi: 10.1039/c5sc01819f. Epub 2015 Jun 17.

Metal influence on the iso- and hetero-selectivity of complexes of bipyrrolidine derived salan ligands for the polymerisation of .

Chemical science

Matthew D Jones, Lauren Brady, Paul McKeown, Antoine Buchard, Pascal M Schäfer, Lynne H Thomas, Mary F Mahon, Timothy J Woodman, John P Lowe

Affiliations

  1. Department of Chemistry , University of Bath , Claverton Down , Bath BA2 7AY , UK . Email: [email protected] ; ; Tel: +44 (0)1225 384908.
  2. Doctoral Training Centre in Sustainable Chemical Technologies , University of Bath , Bath BA2 7AY , UK.
  3. Bath Chemical Crystallography Unit , Department of Chemistry , University of Bath , Claverton Down , Bath , BA2 7AY , UK.

PMID: 29142728 PMCID: PMC5664169 DOI: 10.1039/c5sc01819f

Abstract

In this paper we have prepared a series of Ti(iv), Hf(iv) and Al(iii) complexes based on bipyrrolidine salan pro-ligands. The Hf(iv) complexes have all been characterised in the solid-state, the chiral ligands coordinate to Hf(iv) in an α-

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