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Huang HL, Liu YR, Huang LH, et al. Achiral polyamine-induced chiral zinc gallophosphates with fused double helix-like strands exhibiting blue to green photoluminescence. Dalton Trans. 2017;46(44):15186-15189doi: 10.1039/c7dt02465g.
Huang, H. L., Liu, Y. R., Huang, L. H., Chiang, R. K., & Wang, S. L. (2017). Achiral polyamine-induced chiral zinc gallophosphates with fused double helix-like strands exhibiting blue to green photoluminescence. Dalton transactions (Cambridge, England : 2003), 46(44), 15186-15189. https://doi.org/10.1039/c7dt02465g
Huang, Hui-Lin, et al. "Achiral polyamine-induced chiral zinc gallophosphates with fused double helix-like strands exhibiting blue to green photoluminescence." Dalton transactions (Cambridge, England : 2003) vol. 46,44 (2017): 15186-15189. doi: https://doi.org/10.1039/c7dt02465g
Huang HL, Liu YR, Huang LH, Chiang RK, Wang SL. Achiral polyamine-induced chiral zinc gallophosphates with fused double helix-like strands exhibiting blue to green photoluminescence. Dalton Trans. 2017 Nov 14;46(44):15186-15189. doi: 10.1039/c7dt02465g. PMID: 29068024.
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Dalton Trans. 2017 Nov 14;46(44):15186-15189. doi: 10.1039/c7dt02465g.

Achiral polyamine-induced chiral zinc gallophosphates with fused double helix-like strands exhibiting blue to green photoluminescence.

Dalton transactions (Cambridge, England : 2003)

Hui-Lin Huang, You-Rong Liu, Li-Hsun Huang, Ray-Kuang Chiang, Sue-Lein Wang

Affiliations

  1. Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan. [email protected].

PMID: 29068024 DOI: 10.1039/c7dt02465g

Abstract

This study found non-chiral polyamines to be effective in inducing chiral frameworks. Four zinc gallophosphates with a chiral UCSB-7 topology were generated from the use of four different linear-chain polyamines as templates. In the structure, helical inorganic strands and templates appeared to fuse into a double helix-like arrangement. Notably, they are the first chiral frameworks to display optical analogues and intriguing photoluminescence properties.

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