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Sci Rep. 2017 Nov 10;7(1):15345. doi: 10.1038/s41598-017-15713-x.

Rapid and selective surface functionalization of the membrane for high efficiency oil-water separation via an atmospheric pressure plasma process.

Scientific reports

Yong Sung You, Seongchan Kang, Rodolphe Mauchauffé, Se Youn Moon

Affiliations

  1. Department of Quantum System Engineering, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do, 54896, Republic of Korea.
  2. Department of Applied Plasma Engineering, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do, 54896, Republic of Korea.
  3. Department of Quantum System Engineering, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do, 54896, Republic of Korea. [email protected].
  4. Department of Applied Plasma Engineering, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do, 54896, Republic of Korea. [email protected].

PMID: 29127412 PMCID: PMC5681647 DOI: 10.1038/s41598-017-15713-x

Abstract

Oil-water separation is a worldwide challenge because of the increasing production of industrial oily wastewater and frequent oil spills. The growing environmental and economic demands emphasize the need to develop effective solutions to separate oil and water. Recently, oil-water separation methods were developed by tuning the wettability of membranes via surface functionalization. However, the industrialization of such methods remains challenging due to the easy-fouling, high cost and complex fabrication. Herein, a simple and rapid pathway to separate oil from oil-water mixtures is reported using plasma surface functionalization in an open-air environment. The fine tuning and study of the plasma process parameters enables the selective functionalization of each side of the membranes which led respectively to a superhydrophobic-superoleophilic and superhydrophobic-oleophobic sides. The successful separation, without any external force, of a 50 mL oil-water solution in 6 minutes was achieved. This work paves the way for an efficient, low cost and easily upscalable method for oil-water separation due to the high versatility of the atmospheric pressure plasma processes.

References

  1. Adv Mater. 2011 Jul 5;23(25):2861-4 - PubMed
  2. Adv Sci (Weinh). 2016 Mar 02;3(7):1500413 - PubMed
  3. Adv Mater. 2014 Jan 22;26(3):418-23 - PubMed
  4. Biofouling. 2006;22(5-6):339-60 - PubMed
  5. Adv Mater. 2011 Feb 1;23 (5):673-8 - PubMed
  6. Adv Mater. 2012 Nov 14;24(43):5838-43 - PubMed
  7. Langmuir. 2012 Jul 3;28(26):10015-9 - PubMed
  8. Sci Rep. 2013 Sep 27;3:2776 - PubMed
  9. Science. 1999 Feb 12;283(5404):963-5 - PubMed
  10. Nat Mater. 2003 Jun;2(6):413-8 - PubMed
  11. Sci Rep. 2013;3:2326 - PubMed
  12. Adv Mater. 2011 Oct 4;23(37):4270-3 - PubMed
  13. Langmuir. 2008 Mar 4;24(5):1640-3 - PubMed
  14. Nat Nanotechnol. 2008 Jun;3(6):320-1 - PubMed
  15. Science. 2007 Dec 7;318(5856):1618-22 - PubMed
  16. Adv Mater. 2011 Feb 8;23(6):719-34 - PubMed
  17. Angew Chem Int Ed Engl. 2001 May 4;40(9):1743-1746 - PubMed

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