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Chemistry. 2018 Mar 12;24(15):3659-3670. doi: 10.1002/chem.201704637. Epub 2017 Dec 12.

Synthetic Approaches to Trifluoromethylselenolated Compounds.

Chemistry (Weinheim an der Bergstrasse, Germany)

Anis Tlili, Ermal Ismalaj, Quentin Glenadel, Clément Ghiazza, Thierry Billard

Affiliations

  1. Institute of Chemistry and Biochemistry (ICBMS-UMR CNRS 5246), Univ Lyon, Université Lyon 1, CNRS, 43 Bd du 11 Novembre 1918, 69622, Villeurbanne, France.
  2. CERMEP-in vivo imaging, Groupement Hospitalier Est, 59 Bd Pinel, 69003, Lyon, France.

PMID: 29072337 DOI: 10.1002/chem.201704637

Abstract

The association of trifluoromethyl group to chalcogens gives new fluorinated substituents with specific properties, mainly in term of lipophilicity. The trifluoromethylselenyl group is the last of the series that has been studied and despite pioneering approaches in the late 1960s, CF

© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: Ruppert-Prakash reagent; fluorine; selenenium; selenocyanate; trifluoromethylselenyl

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