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Angew Chem Int Ed Engl. 2017 Dec 22;56(52):16503-16506. doi: 10.1002/anie.201709910. Epub 2017 Nov 30.

Proton-Coupled Reduction of the Catalytic [4Fe-4S] Cluster in [FeFe]-Hydrogenases.

Angewandte Chemie (International ed. in English)

Moritz Senger, Konstantin Laun, Florian Wittkamp, Jifu Duan, Michael Haumann, Thomas Happe, Martin Winkler, Ulf-Peter Apfel, Sven T Stripp

Affiliations

  1. Department of Physics, Freie Universität Berlin, Arnimallee 14, 1495, Berlin, Germany.
  2. Faculty of Chemistry and Biochemistry, Ruhr-Universität Bochum, Universitätstrasse 150, 44801, Bochum, Germany.
  3. Faculty of Biology and Biotechnology, Ruhr-Universität Bochum, Universitätsstrasse 150, 44801, Bochum, Germany.

PMID: 29072356 DOI: 10.1002/anie.201709910

Abstract

In nature, [FeFe]-hydrogenases catalyze the uptake and release of molecular hydrogen (H

© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: biocatalysis; electrochemistry; hydrogen turnover; infrared spectroscopy; proton-coupled electron transfer

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