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Rugg BK, Phelan BT, Horwitz NE, et al. Spin-Selective Photoreduction of a Stable Radical within a Covalent Donor-Acceptor-Radical Triad. J Am Chem Soc. 2017;139(44):15660-15663doi: 10.1021/jacs.7b10458.
Rugg, B. K., Phelan, B. T., Horwitz, N. E., Young, R. M., Krzyaniak, M. D., Ratner, M. A., & Wasielewski, M. R. (2017). Spin-Selective Photoreduction of a Stable Radical within a Covalent Donor-Acceptor-Radical Triad. Journal of the American Chemical Society, 139(44), 15660-15663. https://doi.org/10.1021/jacs.7b10458
Rugg, Brandon K, et al. "Spin-Selective Photoreduction of a Stable Radical within a Covalent Donor-Acceptor-Radical Triad." Journal of the American Chemical Society vol. 139,44 (2017): 15660-15663. doi: https://doi.org/10.1021/jacs.7b10458
Rugg BK, Phelan BT, Horwitz NE, Young RM, Krzyaniak MD, Ratner MA, Wasielewski MR. Spin-Selective Photoreduction of a Stable Radical within a Covalent Donor-Acceptor-Radical Triad. J Am Chem Soc. 2017 Nov 08;139(44):15660-15663. doi: 10.1021/jacs.7b10458. Epub 2017 Oct 31. PMID: 29072446.
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J Am Chem Soc. 2017 Nov 08;139(44):15660-15663. doi: 10.1021/jacs.7b10458. Epub 2017 Oct 31.

Spin-Selective Photoreduction of a Stable Radical within a Covalent Donor-Acceptor-Radical Triad.

Journal of the American Chemical Society

Brandon K Rugg, Brian T Phelan, Noah E Horwitz, Ryan M Young, Matthew D Krzyaniak, Mark A Ratner, Michael R Wasielewski

Affiliations

  1. Department of Chemistry and Institute for Sustainability and Energy at Northwestern, Northwestern University , Evanston, Illinois 60208-3113, United States.

PMID: 29072446 DOI: 10.1021/jacs.7b10458

Abstract

Controlling spin-spin interactions in multispin molecular assemblies is important for developing new approaches to quantum information processing. In this work, a covalent electron donor-acceptor-radical triad is used to probe spin-selective reduction of the stable radical to its diamagnetic anion. The molecule consists of a perylene electron donor chromophore (D) bound to a pyromellitimide acceptor (A), which is, in turn, linked to a stable α,γ-bisdiphenylene-β-phenylallyl radical (R

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