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J Air Waste Manag Assoc. 1999 Sep;49(9):69-75. doi: 10.1080/10473289.1999.10463883.

Determination of PM.

Journal of the Air & Waste Management Association (1995)

Delbert J Eatough, Yanbo Pang, Norman L Eatough

Affiliations

  1. a Department of Chemistry and Biochemistry , Brigham Young University , Provo , Utah , USA.
  2. b Department of Chemistry , California Polytechnic University , San Luis Obispo , California , USA.

PMID: 29073859 DOI: 10.1080/10473289.1999.10463883

Abstract

Ambient particles contain substantial quantities of material that can be lost from the particles during sample collection on a filter. These include ammonium nitrate and semi-volatile organic compounds. As a result, the concentrations of these species are often significantly in error for results obtained with a filter pack sampler. The accurate measurement of these semi-volatile fine particulate species is essential for a complete understanding of the possible causes of health effects associated with exposure to fine particles. Past organic compound diffusion denuder samplers developed by the authors (e.g., the Brigham Young University Organic Sampling System [BOSS]) are not amenable to routine field use because of the need to independently determine the gas-phase semi-volatile organic material efficiency of the denuder for each sample. This problem has been eliminated using a combined virtual impactor, particle-concentrator inlet to provide a concentrated stream of 0.1-2.5-μm particles. This is followed by a BOSS diffusion denuder and filter packs to collect particles, including any semi-volatile species lost from the particles during sampling. The samp ler (Particle Concentrator-Brigham Young University Organic Sampling System [PC-BOSS]) contains a post-denuder multifilter pack unit to allow for the routine collection of several sequential samples. The PC-BOSS can be used for the determination of both fine particulate nitrate and semi-volatile organic material without significant "positive" or "negative" sampling artifacts. Validation of the sampler for the determination of PM

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