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Dalton Trans. 2017 Dec 21;46(47):16605-16614. doi: 10.1039/c7dt03622a. Epub 2017 Nov 22.

The lone-pair-electron-driven phase transition and order-disorder processes in thermochromic (2-MIm)SbI.

Dalton transactions (Cambridge, England : 2003)

A Gągor, G Banach, M Węcławik, A Piecha-Bisiorek, R Jakubas

Affiliations

  1. W. Trzebiatowski Institute of Low Temperature and Structure Research PAS, P.O. Box 1410, 50-950 Wroc?aw, Poland. [email protected].
  2. Institute of Physics, University of Zielona Góra, ul. Prof. Szafrana 4a, 65-516 Zielona Góra, Poland.
  3. Faculty of Chemistry, University of Wroc?aw, Joliot-Curie 14, 50-383 Wroc?aw, Poland.

PMID: 29165466 DOI: 10.1039/c7dt03622a

Abstract

The easy to prepare and stable in air (2-methylimidazolium) tetraiodoantimoniate(iii) single-crystals with optical band gap of 2.17(1) eV at room temperature have been synthesized. The crystal structure features one-dimensional [SbI

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