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Chemistry. 2018 Jan 19;24(4):822-825. doi: 10.1002/chem.201705754. Epub 2017 Dec 27.

Synthesis, Structure, and Acidity Constants of Ligated α-Boryl Acetic Acids.

Chemistry (Weinheim an der Bergstrasse, Germany)

Thomas H Allen, Anthony R Horner, Steven J Geib, Stephen G Weber, Dennis P Curran

Affiliations

  1. Department of Chemistry, University of Pittsburgh, Pittsburgh, PA, 15260, USA.

PMID: 29207202 DOI: 10.1002/chem.201705754

Abstract

Basic hydrolyses of various ligated α-boryl acetic acid esters provided the first ligated derivatives of the unknown compound boroacetic acid (BH

© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: acidity constant measurements; amines; boranes; boryl acetic acids; hydrolysis

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