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Inorg Chem. 2017 Dec 18;56(24):15026-15040. doi: 10.1021/acs.inorgchem.7b02320. Epub 2017 Nov 29.

Si.

Inorganic chemistry

Alena N Kulakova, Alexey N Bilyachenko, Mikhail M Levitsky, Victor N Khrustalev, Alexander A Korlyukov, Yan V Zubavichus, Pavel V Dorovatovskii, Frédéric Lamaty, Xavier Bantreil, Benoît Villemejeanne, Jean Martinez, Lidia S Shul'pina, Elena S Shubina, Evgeniy I Gutsul, Igor A Mikhailov, Nikolay S Ikonnikov, Ul'yana S Tsareva, Georgiy B Shul'pin

Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences , Vavilov Str., 28, Moscow, Russia.
  2. Peoples' Friendship University of Russia (RUDN University) , Miklukho-Maklay Str., 6, Moscow, Russia.
  3. Pirogov Russian National Research Medical University , Ostrovitianov str., 1, Moscow, Russia.
  4. National Research Center "Kurchatov Institute" , Akademika Kurchatova pl., 1, Moscow, Russia.
  5. Institut des Biomolécules Max Mousseron (IBMM), UMR 5247, CNRS, Université de Montpellier, ENSCM , Site Triolet, Place Eugène Bataillon, 34095 Montpellier cedex 5, France.
  6. Plekhanov Russian University of Economics , Stremyannyi pereulok, dom 36, Moscow, Russia.
  7. Semenov Institute of Chemical Physics, Russian Academy of Sciences , ulitsa Kosygina, dom 4, Moscow, Russia.

PMID: 29185729 DOI: 10.1021/acs.inorgchem.7b02320

Abstract

The synthesis, composition, and catalytic properties of a new family of hexanuclear Cu(II)-based phenylsilsesquioxanes are described here. Structural studies of 17 synthesized compounds revealed the general principle underlying their molecular topology: viz., a central metal oxide layer consisting of two Cu

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