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Hua YZ, Chen JW, Yang H, et al. Asymmetric Friedel-Crafts Alkylation of Indoles with Trifluoromethyl Pyruvate Catalyzed by a Dinuclear Zinc Catalyst. J Org Chem. 2018;83(3):1160-1166doi: 10.1021/acs.joc.7b02599.
Hua, Y. Z., Chen, J. W., Yang, H., & Wang, M. C. (2018). Asymmetric Friedel-Crafts Alkylation of Indoles with Trifluoromethyl Pyruvate Catalyzed by a Dinuclear Zinc Catalyst. The Journal of organic chemistry, 83(3), 1160-1166. https://doi.org/10.1021/acs.joc.7b02599
Hua, Yuan-Zhao, et al. "Asymmetric Friedel-Crafts Alkylation of Indoles with Trifluoromethyl Pyruvate Catalyzed by a Dinuclear Zinc Catalyst." The Journal of organic chemistry vol. 83,3 (2018): 1160-1166. doi: https://doi.org/10.1021/acs.joc.7b02599
Hua YZ, Chen JW, Yang H, Wang MC. Asymmetric Friedel-Crafts Alkylation of Indoles with Trifluoromethyl Pyruvate Catalyzed by a Dinuclear Zinc Catalyst. J Org Chem. 2018 Feb 02;83(3):1160-1166. doi: 10.1021/acs.joc.7b02599. Epub 2018 Jan 16. PMID: 29294293.
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J Org Chem. 2018 Feb 02;83(3):1160-1166. doi: 10.1021/acs.joc.7b02599. Epub 2018 Jan 16.

Asymmetric Friedel-Crafts Alkylation of Indoles with Trifluoromethyl Pyruvate Catalyzed by a Dinuclear Zinc Catalyst.

The Journal of organic chemistry

Yuan-Zhao Hua, Jun-Wei Chen, Hua Yang, Min-Can Wang

Affiliations

  1. College of Chemistry and Molecular Engineering, School of Pharmaceutical Sciences, Zhengzhou University , No. 100, Science Road, Zhengzhou, Henan 450000, P. R. China.

PMID: 29294293 DOI: 10.1021/acs.joc.7b02599

Abstract

A bimetallic cooperative catalysis model has been reported for the asymmetric Friedel-Crafts (F-C) alkylation of indoles with trifluoromethyl pyruvates using Trost's intramolecular dinuclear zinc complex as the catalyst. This dinuclear zinc catalyst was prepared in situ by reacting the chiral ligand (S,S)-L2b with 2 equiv of ZnEt

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