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Phys Chem Chem Phys. 2018 Mar 14;20(11):7428-7437. doi: 10.1039/c7cp07142f.

From ligand exchange to reaction intermediates: what does really happen during the synthesis of emissive complexes?.

Physical chemistry chemical physics : PCCP

P Polzin, I V Eliani, J Ströh, M Braun, N Ruser, N Heidenreich, P Rönfeldt, F Bertram, C Näther, S Wöhlbrandt, M Suta, H Terraschke

Affiliations

  1. Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, Max-Eyth-Str. 2, 24118 Kiel, Germany. [email protected].

PMID: 29323378 DOI: 10.1039/c7cp07142f

Abstract

In situ monitoring of the formation of emissive complexes is essential to enable the development of rational synthesis protocols, to provide accurate control over the generation of structure-related properties (such as luminescence) and to facilitate the development of new compounds. In situ luminescence analysis of coordination sensors (ILACS) utilizes the sensitivity of the spectroscopic properties of lanthanide ions to their coordination environment to detect structural changes during crystallization processes. Here, ILACS was utilized to monitor the formation of [Eu(bipy)

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