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Ritschel B, Poater J, Dengel H, et al. Double CH Activation of a Masked Cationic Bismuth Amide. Angew Chem Int Ed Engl. 2018;57(14):3825-3829doi: 10.1002/anie.201712725.
Ritschel, B., Poater, J., Dengel, H., Bickelhaupt, F. M., & Lichtenberg, C. (2018). Double CH Activation of a Masked Cationic Bismuth Amide. Angewandte Chemie (International ed. in English), 57(14), 3825-3829. https://doi.org/10.1002/anie.201712725
Ritschel, Benedikt, et al. "Double CH Activation of a Masked Cationic Bismuth Amide." Angewandte Chemie (International ed. in English) vol. 57,14 (2018): 3825-3829. doi: https://doi.org/10.1002/anie.201712725
Ritschel B, Poater J, Dengel H, Bickelhaupt FM, Lichtenberg C. Double CH Activation of a Masked Cationic Bismuth Amide. Angew Chem Int Ed Engl. 2018 Mar 26;57(14):3825-3829. doi: 10.1002/anie.201712725. Epub 2018 Mar 01. PMID: 29389062.
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Angew Chem Int Ed Engl. 2018 Mar 26;57(14):3825-3829. doi: 10.1002/anie.201712725. Epub 2018 Mar 01.

Double CH Activation of a Masked Cationic Bismuth Amide.

Angewandte Chemie (International ed. in English)

Benedikt Ritschel, Jordi Poater, Hannah Dengel, F Matthias Bickelhaupt, Crispin Lichtenberg

Affiliations

  1. Department of Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
  2. ICREA, Pg. Lluís Companys 23, 08010, Barcelona, Spain.
  3. Universitat de Barcelona, Departament de Química Inorgànica i Orgànica & IQTCUB, Martí i Franquès 1-11, 08028, Barcelona, Catalonia, Spain.
  4. Department of Theoretical Chemistry, Amsterdam Center for Multiscale Modelling (ACMM), Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081, HV, Amsterdam, The Netherlands.
  5. Radboud University, Institute for Molecules and Materials, Heyendaalseweg 135, 6525, AJ, Nijmegen, The Netherlands.

PMID: 29389062 DOI: 10.1002/anie.201712725

Abstract

The transformation of C-H bonds into more reactive C-M bonds amenable to further functionalization is of fundamental importance in synthetic chemistry. We demonstrate here that the transformation of neutral bismuth compounds into their cationic analogues can be used as a strategy to facilitate CH activation reactions. In particular, the double CH activation of bismuth-bound diphenyl amide, (NPh

© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: CH activation; aromaticity; bismuth; cationic species; density functional calculations

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