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Shibuta S, Imamura H. Hydration Promoted by a Methylene Group: A Volumetric Study on Alkynes in Water. J Phys Chem B. 2018;122(11):2985-2991doi: 10.1021/acs.jpcb.8b00843.
Shibuta, S., & Imamura, H. (2018). Hydration Promoted by a Methylene Group: A Volumetric Study on Alkynes in Water. The journal of physical chemistry. B, 122(11), 2985-2991. https://doi.org/10.1021/acs.jpcb.8b00843
Shibuta, Satoshi, and Imamura, Hiroshi. "Hydration Promoted by a Methylene Group: A Volumetric Study on Alkynes in Water." The journal of physical chemistry. B vol. 122,11 (2018): 2985-2991. doi: https://doi.org/10.1021/acs.jpcb.8b00843
Shibuta S, Imamura H. Hydration Promoted by a Methylene Group: A Volumetric Study on Alkynes in Water. J Phys Chem B. 2018 Mar 22;122(11):2985-2991. doi: 10.1021/acs.jpcb.8b00843. Epub 2018 Mar 09. PMID: 29486128.
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J Phys Chem B. 2018 Mar 22;122(11):2985-2991. doi: 10.1021/acs.jpcb.8b00843. Epub 2018 Mar 09.

Hydration Promoted by a Methylene Group: A Volumetric Study on Alkynes in Water.

The journal of physical chemistry. B

Satoshi Shibuta, Hiroshi Imamura

Affiliations

  1. Chiba Institute of Technology , 2-1-1 Shibazono , Narashino , Chiba 275-0023 , Japan.
  2. Department of Applied Chemistry , College of Life Sciences, Ritsumeikan University , 1-1-1 Noji-Higashi , Kusatsu , Shiga 525-8577 , Japan.

PMID: 29486128 DOI: 10.1021/acs.jpcb.8b00843

Abstract

Hydrocarbons including a methylene group are generally considered a hydrophobic building block, in the sense that the density of their hydration water is lower than that of bulk water. However, is the methylene group always hydrophobic? In this study, we experimentally determined the partial molar volume of a methylene group in water as 14.01 ± 0.46 cm

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