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Qiu Y, Kong WJ, Struwe J, et al. Electrooxidative Rhodium-Catalyzed C-H/C-H Activation: Electricity as Oxidant for Cross-Dehydrogenative Alkenylation. Angew Chem Int Ed Engl. 2018;57(20):5828-5832doi: 10.1002/anie.201803342.
Qiu, Y., Kong, W. J., Struwe, J., Sauermann, N., Rogge, T., Scheremetjew, A., & Ackermann, L. (2018). Electrooxidative Rhodium-Catalyzed C-H/C-H Activation: Electricity as Oxidant for Cross-Dehydrogenative Alkenylation. Angewandte Chemie (International ed. in English), 57(20), 5828-5832. https://doi.org/10.1002/anie.201803342
Qiu, Youai, et al. "Electrooxidative Rhodium-Catalyzed C-H/C-H Activation: Electricity as Oxidant for Cross-Dehydrogenative Alkenylation." Angewandte Chemie (International ed. in English) vol. 57,20 (2018): 5828-5832. doi: https://doi.org/10.1002/anie.201803342
Qiu Y, Kong WJ, Struwe J, Sauermann N, Rogge T, Scheremetjew A, Ackermann L. Electrooxidative Rhodium-Catalyzed C-H/C-H Activation: Electricity as Oxidant for Cross-Dehydrogenative Alkenylation. Angew Chem Int Ed Engl. 2018 May 14;57(20):5828-5832. doi: 10.1002/anie.201803342. Epub 2018 Apr 23. PMID: 29633454.
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Angew Chem Int Ed Engl. 2018 May 14;57(20):5828-5832. doi: 10.1002/anie.201803342. Epub 2018 Apr 23.

Electrooxidative Rhodium-Catalyzed C-H/C-H Activation: Electricity as Oxidant for Cross-Dehydrogenative Alkenylation.

Angewandte Chemie (International ed. in English)

Youai Qiu, Wei-Jun Kong, Julia Struwe, Nicolas Sauermann, Torben Rogge, Alexej Scheremetjew, Lutz Ackermann

Affiliations

  1. Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, 37077, Göttingen, Germany.

PMID: 29633454 DOI: 10.1002/anie.201803342

Abstract

Rhodium(III) catalysis has enabled a plethora of oxidative C-H functionalizations, which predominantly employ stoichiometric amounts of toxic and/or expensive metal oxidants. In contrast, we herein describe the first electrochemical rhodium-catalyzed C-H activation that avoids hazardous chemical oxidants. Environmentally benign twofold C-H/C-H functionalizations were accomplished with weakly coordinating benzoic acids and benzamides, employing electricity as the terminal oxidant and generating H

© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: C−H activation; electrocatalysis; electrooxidation; olefination; rhodium

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