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Ando N, Kushida T, Yamaguchi S. A planarized B-phenyldibenzoborepin: impact of structural constraint on its electronic properties and Lewis acidity. Chem Commun (Camb). 2018;54(41):5213-5216doi: 10.1039/c8cc02837k.
Ando, N., Kushida, T., & Yamaguchi, S. (2018). A planarized B-phenyldibenzoborepin: impact of structural constraint on its electronic properties and Lewis acidity. Chemical communications (Cambridge, England), 54(41), 5213-5216. https://doi.org/10.1039/c8cc02837k
Ando, Naoki, et al. "A planarized B-phenyldibenzoborepin: impact of structural constraint on its electronic properties and Lewis acidity." Chemical communications (Cambridge, England) vol. 54,41 (2018): 5213-5216. doi: https://doi.org/10.1039/c8cc02837k
Ando N, Kushida T, Yamaguchi S. A planarized B-phenyldibenzoborepin: impact of structural constraint on its electronic properties and Lewis acidity. Chem Commun (Camb). 2018 May 17;54(41):5213-5216. doi: 10.1039/c8cc02837k. PMID: 29722377.
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Chem Commun (Camb). 2018 May 17;54(41):5213-5216. doi: 10.1039/c8cc02837k.

A planarized B-phenyldibenzoborepin: impact of structural constraint on its electronic properties and Lewis acidity.

Chemical communications (Cambridge, England)

Naoki Ando, Tomokatsu Kushida, Shigehiro Yamaguchi

Affiliations

  1. Department of Chemistry, Graduate School of Science, Nagoya University, Furo, Chikusa, Nagoya, 464-8602, Japan.

PMID: 29722377 DOI: 10.1039/c8cc02837k

Abstract

A B-phenyldibenzo[b,f]borepin planarized with two methylene bridges was synthesized. The structural constraint on the B-phenyl group resulted in a bathochromic shift of the absorption and fluorescence properties as well as enhanced Lewis acidity. A donor-π-acceptor type derivative based on this scaffold exhibited intense fluorescence irrespective of the solvent polarity.

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