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Tingare YS, Akula SB, Shen MT, et al. The effect of cis-trans configurational difference on the performance of pyridylimine-based ruthenium sensitizers. Dalton Trans. 2018;47(25):8356-8363doi: 10.1039/c8dt01131a.
Tingare, Y. S., Akula, S. B., Shen, M. T., Su, C., Ho, S. Y., Tsai, S. H., Lin, Y. F., & Li, W. R. (2018). The effect of cis-trans configurational difference on the performance of pyridylimine-based ruthenium sensitizers. Dalton transactions (Cambridge, England : 2003), 47(25), 8356-8363. https://doi.org/10.1039/c8dt01131a
Tingare, Yogesh S, et al. "The effect of cis-trans configurational difference on the performance of pyridylimine-based ruthenium sensitizers." Dalton transactions (Cambridge, England : 2003) vol. 47,25 (2018): 8356-8363. doi: https://doi.org/10.1039/c8dt01131a
Tingare YS, Akula SB, Shen MT, Su C, Ho SY, Tsai SH, Lin YF, Li WR. The effect of cis-trans configurational difference on the performance of pyridylimine-based ruthenium sensitizers. Dalton Trans. 2018 Jun 25;47(25):8356-8363. doi: 10.1039/c8dt01131a. PMID: 29897066.
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Dalton Trans. 2018 Jun 25;47(25):8356-8363. doi: 10.1039/c8dt01131a.

The effect of cis-trans configurational difference on the performance of pyridylimine-based ruthenium sensitizers.

Dalton transactions (Cambridge, England : 2003)

Yogesh S Tingare, Suri Babu Akula, Ming-Tai Shen, Chaochin Su, Shih-Yu Ho, Sheng-Han Tsai, Ya-Fen Lin, Wen-Ren Li

Affiliations

  1. Department of Chemistry, National Central University, Chung-Li, Taiwan. ch01@ ncu.edu.tw.

PMID: 29897066 DOI: 10.1039/c8dt01131a

Abstract

New heteroleptic Ru(ii) complexes consisting of pyridylimine as an ancillary ligand were synthesized and characterized for applications in dye sensitized solar cells. Complexes with cis and trans configurations around the central ruthenium metal were obtained using simple synthetic protocols by varying the substituents on the pyridylimine ligands. The geometries of these complexes were confirmed by single crystal X-ray analysis. The effect of the difference in the configurations of these complexes on their device performances was studied and the sensitizer with a trans arrangement around the metal showed a higher overall conversion efficiency (η) of 7.27% than that of the cis configured complex (η = 2.04%).

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