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Vanagas NA, Wacker JN, Rom CL, et al. Solution and Solid State Structural Chemistry of Th(IV) and U(IV) 4-Hydroxybenzoates. Inorg Chem. 2018;57(12):7259-7269doi: 10.1021/acs.inorgchem.8b00919.
Vanagas, N. A., Wacker, J. N., Rom, C. L., Glass, E. N., Colliard, I., Qiao, Y., Bertke, J. A., Van Keuren, E., Schelter, E. J., Nyman, M., & Knope, K. E. (2018). Solution and Solid State Structural Chemistry of Th(IV) and U(IV) 4-Hydroxybenzoates. Inorganic chemistry, 57(12), 7259-7269. https://doi.org/10.1021/acs.inorgchem.8b00919
Vanagas, Nicole A, et al. "Solution and Solid State Structural Chemistry of Th(IV) and U(IV) 4-Hydroxybenzoates." Inorganic chemistry vol. 57,12 (2018): 7259-7269. doi: https://doi.org/10.1021/acs.inorgchem.8b00919
Vanagas NA, Wacker JN, Rom CL, Glass EN, Colliard I, Qiao Y, Bertke JA, Van Keuren E, Schelter EJ, Nyman M, Knope KE. Solution and Solid State Structural Chemistry of Th(IV) and U(IV) 4-Hydroxybenzoates. Inorg Chem. 2018 Jun 18;57(12):7259-7269. doi: 10.1021/acs.inorgchem.8b00919. Epub 2018 Jun 07. PMID: 29877086.
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Inorg Chem. 2018 Jun 18;57(12):7259-7269. doi: 10.1021/acs.inorgchem.8b00919. Epub 2018 Jun 07.

Solution and Solid State Structural Chemistry of Th(IV) and U(IV) 4-Hydroxybenzoates.

Inorganic chemistry

Nicole A Vanagas, Jennifer N Wacker, Christopher L Rom, Elliot N Glass, Ian Colliard, Yusen Qiao, Jeffery A Bertke, Edward Van Keuren, Eric J Schelter, May Nyman, Karah E Knope

Affiliations

  1. Department of Chemistry , Georgetown University , 37th and O Streets Northwest , Washington, D.C. 20057 , United States.
  2. Department of Chemistry , Oregon State University , Corvallis , Oregon 97331 , United States.
  3. P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry , University of Pennsylvania , 231 South 34th Street , Philadelphia , Pennsylvania 19104 , United States.
  4. Department of Physics , Georgetown University , 37th and O Streets Northwest , Washington, D.C. 20057 , United States.

PMID: 29877086 DOI: 10.1021/acs.inorgchem.8b00919

Abstract

Organic ligands with carboxylate functionalities have been shown to affect the solubility, speciation, and overall chemical behavior of tetravalent metal ions. While many reports have focused on actinide complexation by relatively simple monocarboxylates such as amino acids, in this work we examined Th(IV) and U(IV) complexation by 4-hydroxybenzoic acid in water with the aim of understanding the impact that the organic backbone has on the solution and solid state structural chemistry of thorium(IV) and uranium(IV) complexes. Two compounds of the general formula [An

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