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Inorg Chem. 2018 Jul 16;57(14):8218-8226. doi: 10.1021/acs.inorgchem.8b00719. Epub 2018 Jun 26.

Designing Stability into Thermally Reactive Plumbylenes.

Inorganic chemistry

Goran Bačić, David Zanders, Bert Mallick, Anjana Devi, Seán T Barry

Affiliations

  1. Department of Chemistry , Carleton University , 1125 Colonel By Drive , Ottawa , Ontario K1S 5B6 , Canada.

PMID: 29943579 DOI: 10.1021/acs.inorgchem.8b00719

Abstract

Lead analogues of N-heterocyclic carbenes (NHPbs) are the least understood members of this increasingly important class of compounds. Here we report the design, preparation, isolation, structure, volatility, and decomposition pathways of a novel aliphatic NHPb: rac- N 

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