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Ye TN, Li J, Kitano M, et al. Electronic interactions between a stable electride and a nano-alloy control the chemoselective reduction reaction. Chem Sci. 2016;7(9):5969-5975doi: 10.1039/c6sc01864e.
Ye, T. N., Li, J., Kitano, M., Sasase, M., & Hosono, H. (2016). Electronic interactions between a stable electride and a nano-alloy control the chemoselective reduction reaction. Chemical science, 7(9), 5969-5975. https://doi.org/10.1039/c6sc01864e
Ye, Tian-Nan, et al. "Electronic interactions between a stable electride and a nano-alloy control the chemoselective reduction reaction." Chemical science vol. 7,9 (2016): 5969-5975. doi: https://doi.org/10.1039/c6sc01864e
Ye TN, Li J, Kitano M, Sasase M, Hosono H. Electronic interactions between a stable electride and a nano-alloy control the chemoselective reduction reaction. Chem Sci. 2016 Sep 01;7(9):5969-5975. doi: 10.1039/c6sc01864e. Epub 2016 May 24. PMID: 30034737; PMCID: PMC6022174.
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Chem Sci. 2016 Sep 01;7(9):5969-5975. doi: 10.1039/c6sc01864e. Epub 2016 May 24.

Electronic interactions between a stable electride and a nano-alloy control the chemoselective reduction reaction.

Chemical science

Tian-Nan Ye, Jiang Li, Masaaki Kitano, Masato Sasase, Hideo Hosono

Affiliations

  1. Materials Research Center for Element Strategy , Tokyo Institute of Technology , 4259 Nagatsuta, Midori-ku , Yokohama 226-8503 , Japan . Email: [email protected] ; Email: [email protected].
  2. Laboratory for Materials and Structures , Tokyo Institute of Technology , 4259 Nagatsuta, Midori-ku , Yokohama 226-8503 , Japan.
  3. ACCEL , Japan Science and Technology Agency , 4-1-8 Honcho, Kawaguchi , Saitama 332-0012 , Japan.

PMID: 30034737 PMCID: PMC6022174 DOI: 10.1039/c6sc01864e

Abstract

Controlling the electronic structure of heterogeneous metal catalysts is considered an efficient method to optimize catalytic activity. Here, we introduce a new electronic effect induced by the synergy of a stable electride and bimetallic nanoparticles for a chemoselective reduction reaction. The electride [Ca

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