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Angew Chem Int Ed Engl. 2018 Nov 26;57(48):15717-15722. doi: 10.1002/anie.201809158. Epub 2018 Nov 02.

Observation of Carbodicarbene Ligand Redox Noninnocence in Highly Oxidized Iron Complexes.

Angewandte Chemie (International ed. in English)

Siu-Chung Chan, Puneet Gupta, Xenia Engelmann, Zhi Zhong Ang, Rakesh Ganguly, Eckhard Bill, Kallol Ray, Shengfa Ye, Jason England

Affiliations

  1. Division of Chemistry and Biological Chemistry, School of Physical & Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore, 637371, Singapore.
  2. Max-Plank-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470, Mülheim an der Ruhr, Germany.
  3. Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489, Berlin, Germany.
  4. Max-Plank-Institut für Chemische Energie Konversion, Stiftstraße 34-36, 45470, Mülheim an der Ruhr, Germany.

PMID: 30239076 DOI: 10.1002/anie.201809158

Abstract

To probe the possibility that carbodicarbenes (CDCs) are redox active ligands, all four members of the redox series [Fe(1)

© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: carbodicarbenes; cationic ligands; iron; radical ions; redox noninnocence

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Grant support