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Skalski TJG, Adamski M, Britton B, et al. Sulfophenylated Terphenylene Copolymer Membranes and Ionomers. ChemSusChem. 2018;11(23):4033-4043doi: 10.1002/cssc.201801965.
Skalski, T. J. G., Adamski, M., Britton, B., Schibli, E. M., Peckham, T. J., Weissbach, T., Moshisuki, T., Lyonnard, S., Frisken, B. J., & Holdcroft, S. (2018). Sulfophenylated Terphenylene Copolymer Membranes and Ionomers. ChemSusChem, 11(23), 4033-4043. https://doi.org/10.1002/cssc.201801965
Skalski, Thomas J G, et al. "Sulfophenylated Terphenylene Copolymer Membranes and Ionomers." ChemSusChem vol. 11,23 (2018): 4033-4043. doi: https://doi.org/10.1002/cssc.201801965
Skalski TJG, Adamski M, Britton B, Schibli EM, Peckham TJ, Weissbach T, Moshisuki T, Lyonnard S, Frisken BJ, Holdcroft S. Sulfophenylated Terphenylene Copolymer Membranes and Ionomers. ChemSusChem. 2018 Dec 11;11(23):4033-4043. doi: 10.1002/cssc.201801965. Epub 2018 Nov 07. PMID: 30251343.
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ChemSusChem. 2018 Dec 11;11(23):4033-4043. doi: 10.1002/cssc.201801965. Epub 2018 Nov 07.

Sulfophenylated Terphenylene Copolymer Membranes and Ionomers.

ChemSusChem

Thomas J G Skalski, Michael Adamski, Benjamin Britton, Eric M Schibli, Timothy J Peckham, Thomas Weissbach, Takashi Moshisuki, Sandrine Lyonnard, Barbara J Frisken, Steven Holdcroft

Affiliations

  1. Department of Chemistry, Simon Fraser University, Burnaby, British Columbia, V5A 1S6, Canada.
  2. Department of Physics, Simon Fraser University, Burnaby, British Columbia, V5A 1S6, Canada.
  3. Interdisciplinary Graduate School of Medicine and Engineering, University of Yamanashi, 4 Takeda, Kofu, Yamanashi, 400-8510, Japan.
  4. INAC, SPrAM, UMR 5819 CEA-CNRS-UJF, CEA Grenoble, 17 rue des Martyrs, 38054, Grenoble cedex 9, France.

PMID: 30251343 DOI: 10.1002/cssc.201801965

Abstract

The copolymerization of a prefunctionalized, tetrasulfonated oligophenylene monomer was investigated. The corresponding physical and electrochemical properties of the polymers were tuned by varying the ratio of hydrophobic to hydrophilic units within the polymers. Membranes prepared from these polymers possessed ion exchange capacities ranging from 1.86 to 3.50 meq g

© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: copolymers; electrochemistry; fuel cells; ionomers; membranes

Publication Types

Grant support