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Dalton Trans. 2018 Oct 30;47(42):15226-15231. doi: 10.1039/c8dt03661f.

Crown-substituted naphthalocyanines: synthesis and supramolecular control over aggregation and photophysical properties.

Dalton transactions (Cambridge, England : 2003)

Evgeniya A Safonova, Marina A Polovkova, Alexander G Martynov, Yulia G Gorbunova, Aslan Yu Tsivadze

Affiliations

  1. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, bldg 4, Moscow, 119071, Russia.

PMID: 30321250 DOI: 10.1039/c8dt03661f

Abstract

Tetra-15-crown-5-naphthalocyanines as first representatives of crown-substituted π-extended phthalocyanines were synthesized and characterized. The possibility to control their aggregation and photophysical properties by reversible formation of supramolecular assemblies in the presence of KOAc was demonstrated.

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