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Sharma HN, Kroonblawd MP, Sun Y, et al. Role of filler and its heterostructure on moisture sorption mechanisms in polyimide films. Sci Rep. 2018;8(1):16889doi: 10.1038/s41598-018-35181-1.
Sharma, H. N., Kroonblawd, M. P., Sun, Y., & Glascoe, E. A. (2018). Role of filler and its heterostructure on moisture sorption mechanisms in polyimide films. Scientific reports, 8(1), 16889. https://doi.org/10.1038/s41598-018-35181-1
Sharma, Hom N, et al. "Role of filler and its heterostructure on moisture sorption mechanisms in polyimide films." Scientific reports vol. 8,1 (2018): 16889. doi: https://doi.org/10.1038/s41598-018-35181-1
Sharma HN, Kroonblawd MP, Sun Y, Glascoe EA. Role of filler and its heterostructure on moisture sorption mechanisms in polyimide films. Sci Rep. 2018 Nov 15;8(1):16889. doi: 10.1038/s41598-018-35181-1. PMID: 30442999; PMCID: PMC6237878.
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Sci Rep. 2018 Nov 15;8(1):16889. doi: 10.1038/s41598-018-35181-1.

Role of filler and its heterostructure on moisture sorption mechanisms in polyimide films.

Scientific reports

Hom N Sharma, Matthew P Kroonblawd, Yunwei Sun, Elizabeth A Glascoe

Affiliations

  1. Lawrence Livermore National Laboratory, 7000 East Ave., Livermore, California, 94550, United States.
  2. Lawrence Livermore National Laboratory, 7000 East Ave., Livermore, California, 94550, United States. [email protected].

PMID: 30442999 PMCID: PMC6237878 DOI: 10.1038/s41598-018-35181-1

Abstract

Moisture sorption and diffusion exacerbate hygrothermal aging and can significantly alter the chemical and mechanical properties of polymeric-based components over time. In this study, we employ a multi-pronged multi-scale approach to model and understand moisture diffusion and sorption processes in polyimide polymers. A reactive transport model with triple-mode sorption (i.e., Henry's, Langmuir, and pooling), experiments, and first principles atomistic computations were combined to synergistically explore representative systems of Kapton H and Kapton HN polymers. We find that the CaHPO

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