Display options
Cite
Aksenov AV, Aksenov NA, Aksenov DA, et al. Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles. Chem Commun (Camb). 2018;54(94):13260-13263doi: 10.1039/c8cc07451h.
Aksenov, A. V., Aksenov, N. A., Aksenov, D. A., Khamraev, V. F., & Rubin, M. (2018). Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles. Chemical communications (Cambridge, England), 54(94), 13260-13263. https://doi.org/10.1039/c8cc07451h
Aksenov, Alexander V, et al. "Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles." Chemical communications (Cambridge, England) vol. 54,94 (2018): 13260-13263. doi: https://doi.org/10.1039/c8cc07451h
Aksenov AV, Aksenov NA, Aksenov DA, Khamraev VF, Rubin M. Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles. Chem Commun (Camb). 2018 Nov 22;54(94):13260-13263. doi: 10.1039/c8cc07451h. PMID: 30411750.
Copy Download .nbib Format: NLM
Share it on

Chem Commun (Camb). 2018 Nov 22;54(94):13260-13263. doi: 10.1039/c8cc07451h.

Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles.

Chemical communications (Cambridge, England)

Alexander V Aksenov, Nicolai A Aksenov, Dmitrii A Aksenov, Vladislav F Khamraev, Michael Rubin

Affiliations

  1. Department of Chemistry, North Caucasus Federal University, 1a Pushkin St., Stavropol 355009, Russian Federation.

PMID: 30411750 DOI: 10.1039/c8cc07451h

Abstract

An unusual reactivity of nitrostyrenes in phosphorous acid was discovered, which permits the employment of these readily available synthons as 1,4-CCNO-dipole surrogates in a highly diastereoselective (4+1)-cycloaddition of indoles to afford 4'H-spiro[indole-3,5'-isoxazoles] in a diastereomerically pure form.

Publication Types