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Gimeno-Prat A, Cortés-Sanchón A, Martín A, et al. Platinum-mediated monohydration of SO. Dalton Trans. 2018;47(47):16846-16849doi: 10.1039/c8dt04169e.
Gimeno-Prat, A., Cortés-Sanchón, A., Martín, A., Baya, M., & Casas, J. M. (2018). Platinum-mediated monohydration of SO. Dalton transactions (Cambridge, England : 2003), 47(47), 16846-16849. https://doi.org/10.1039/c8dt04169e
Gimeno-Prat, Antonio, et al. "Platinum-mediated monohydration of SO." Dalton transactions (Cambridge, England : 2003) vol. 47,47 (2018): 16846-16849. doi: https://doi.org/10.1039/c8dt04169e
Gimeno-Prat A, Cortés-Sanchón A, Martín A, Baya M, Casas JM. Platinum-mediated monohydration of SO. Dalton Trans. 2018 Dec 04;47(47):16846-16849. doi: 10.1039/c8dt04169e. PMID: 30468447.
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Dalton Trans. 2018 Dec 04;47(47):16846-16849. doi: 10.1039/c8dt04169e.

Platinum-mediated monohydration of SO.

Dalton transactions (Cambridge, England : 2003)

Antonio Gimeno-Prat, Adrián Cortés-Sanchón, Antonio Martín, Miguel Baya, José M Casas

Affiliations

  1. Instituto de Síntesis Química y Catálisis Homogénea (iSQCH) CSIC-Universidad de Zaragoza, C/. Pedro Cerbuna 12, ES-50009 Zaragoza, Spain. [email protected] [email protected].

PMID: 30468447 DOI: 10.1039/c8dt04169e

Abstract

The monohydration of SO2 has been achieved in solution mediated by a platinum-aquo complex. Benzamidate ligands play a key role along the process, acting as versatile proton shuttles. Finally, the platinum center allows the stabilization of benzimidic acid and a hydrogensulphite anion, the disfavored tautomers of benzamide and sulphonate, respectively.

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