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Dias GG, Rogge T, Kuniyil R, et al. Ruthenium-catalyzed C-H oxygenation of quinones by weak O-coordination for potent trypanocidal agents. Chem Commun (Camb). 2018;54(91):12840-12843doi: 10.1039/c8cc07572g.
Dias, G. G., Rogge, T., Kuniyil, R., Jacob, C., Menna-Barreto, R. F. S., da Silva Júnior, E. N., & Ackermann, L. (2018). Ruthenium-catalyzed C-H oxygenation of quinones by weak O-coordination for potent trypanocidal agents. Chemical communications (Cambridge, England), 54(91), 12840-12843. https://doi.org/10.1039/c8cc07572g
Dias, Gleiston G, et al. "Ruthenium-catalyzed C-H oxygenation of quinones by weak O-coordination for potent trypanocidal agents." Chemical communications (Cambridge, England) vol. 54,91 (2018): 12840-12843. doi: https://doi.org/10.1039/c8cc07572g
Dias GG, Rogge T, Kuniyil R, Jacob C, Menna-Barreto RFS, da Silva Júnior EN, Ackermann L. Ruthenium-catalyzed C-H oxygenation of quinones by weak O-coordination for potent trypanocidal agents. Chem Commun (Camb). 2018 Nov 13;54(91):12840-12843. doi: 10.1039/c8cc07572g. PMID: 30374498.
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Chem Commun (Camb). 2018 Nov 13;54(91):12840-12843. doi: 10.1039/c8cc07572g.

Ruthenium-catalyzed C-H oxygenation of quinones by weak O-coordination for potent trypanocidal agents.

Chemical communications (Cambridge, England)

Gleiston G Dias, Torben Rogge, Rositha Kuniyil, Claus Jacob, Rubem F S Menna-Barreto, Eufrânio N da Silva Júnior, Lutz Ackermann

Affiliations

  1. Institute of Exact Sciences, Department of Chemistry, Federal University of Minas Gerais, Belo Horizonte, MG, 31270-901, Brazil. [email protected].

PMID: 30374498 DOI: 10.1039/c8cc07572g

Abstract

Ruthenium-catalysis enabled the C-5 selective C-H oxygenation of naphthoquinones, and also sets the stage for the site-selective introduction of a hydroxyl group into anthraquinones. A-ring modified naphthoquinoidal compounds represent an important class of bioactive quinones for which the present study encompasses the first C-H oxygenation strategy by weak O-coordination.

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