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Appl Radiat Isot. 2019 Feb;144:118-123. doi: 10.1016/j.apradiso.2018.11.004. Epub 2018 Nov 15.

Wavelength dispersive X-ray fluorescence determination of major oxides in bottom and peat sediments for paleoclimatic studies.

Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine

Alena A Amosova, Victor M Chubarov, Galina V Pashkova, Alexander L Finkelshtein, Elena V Bezrukova

Affiliations

  1. Laboratory of X-ray analysis, A.P. Vinogradov Institute of Geochemistry, Siberian Branch of the Russian Academy of Sciences, 1A Favorsky St., 664033 Irkutsk, Russia. Electronic address: [email protected].
  2. Laboratory of X-ray analysis, A.P. Vinogradov Institute of Geochemistry, Siberian Branch of the Russian Academy of Sciences, 1A Favorsky St., 664033 Irkutsk, Russia.
  3. Center for Geodynamics and Geochronology, Institute of Earth Crust, Siberian Branch of the Russian Academy of Sciences, 128 Lermontov St., 664033 Irkutsk, Russia.
  4. Laboratory of Environmental Geochemistry and Physical and Chemical Modeling, A.P. Vinogradov Institute of Geochemistry, Siberian Branch of the Russian Academy of Sciences, 1A Favorsky St., 664033 Irkutsk, Russia; Irkutsk Scientific Center of Siberian Branch of the Russian Academy of Sciences, 134 Lermontov St., 664033 Irkutsk, Russia; Federal State Budget Institution Of Higher Education, Tyumen industrial University, 38 Volodarsky St., 625000 Tyumen, Russia.

PMID: 30576942 DOI: 10.1016/j.apradiso.2018.11.004

Abstract

The wavelength dispersive X-ray fluorescence method was applied to identify the distribution of major oxides within bottom and peat sediments containing organic matter of up to 70 wt.%. Samples were prepared as glass beads by fusing with lithium metaborate. The accuracy of results was assessed by flame photometry, spectrophotometry, and flame atomic absorption techniques. The proposed technique requires a sample weighing only 110 mg, which allows to analyze each centimeter of core collected at high-mountainous sites with undisturbed environment and eventually achieve uniquely high resolution of paleoclimatic reconstructions of global and regional climatic and environmental changes.

Copyright © 2018 Elsevier Ltd. All rights reserved.

Keywords: Bottom sediments; Paleoclimate; Peat sediments; Sediment core; Wavelength dispersive X-ray fluorescence analysis

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