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Kinney RG, Arndtsen BA. Decarboxylation with Carbon Monoxide: The Direct Conversion of Carboxylic Acids into Potent Acid Triflate Electrophiles. Angew Chem Int Ed Engl. 2019;58(15):5085-5089doi: 10.1002/anie.201814660.
Kinney, R. G., & Arndtsen, B. A. (2019). Decarboxylation with Carbon Monoxide: The Direct Conversion of Carboxylic Acids into Potent Acid Triflate Electrophiles. Angewandte Chemie (International ed. in English), 58(15), 5085-5089. https://doi.org/10.1002/anie.201814660
Kinney, R Garrison, and Arndtsen, Bruce A. "Decarboxylation with Carbon Monoxide: The Direct Conversion of Carboxylic Acids into Potent Acid Triflate Electrophiles." Angewandte Chemie (International ed. in English) vol. 58,15 (2019): 5085-5089. doi: https://doi.org/10.1002/anie.201814660
Kinney RG, Arndtsen BA. Decarboxylation with Carbon Monoxide: The Direct Conversion of Carboxylic Acids into Potent Acid Triflate Electrophiles. Angew Chem Int Ed Engl. 2019 Apr 01;58(15):5085-5089. doi: 10.1002/anie.201814660. Epub 2019 Mar 05. PMID: 30776306.
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Angew Chem Int Ed Engl. 2019 Apr 01;58(15):5085-5089. doi: 10.1002/anie.201814660. Epub 2019 Mar 05.

Decarboxylation with Carbon Monoxide: The Direct Conversion of Carboxylic Acids into Potent Acid Triflate Electrophiles.

Angewandte Chemie (International ed. in English)

R Garrison Kinney, Bruce A Arndtsen

Affiliations

  1. Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, QC, H3A 0B8, Canada.

PMID: 30776306 DOI: 10.1002/anie.201814660

Abstract

We report a new strategy for the conversion of carboxylic acids into potent acid triflate electrophiles. The reaction involves oxidative carbonylation of carboxylic acids with I

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: acylation; carbonylation; decarboxylation; iodination; ketones

Publication Types

Grant support