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Bole LJ, Davin L, Kennedy AR, et al. Magnesium-mediated arylation of amines via C-F bond activation of fluoroarenes. Chem Commun (Camb). 2019;55(30):4339-4342doi: 10.1039/c9cc01670h.
Bole, L. J., Davin, L., Kennedy, A. R., McLellan, R., & Hevia, E. (2019). Magnesium-mediated arylation of amines via C-F bond activation of fluoroarenes. Chemical communications (Cambridge, England), 55(30), 4339-4342. https://doi.org/10.1039/c9cc01670h
Bole, Leonie J, et al. "Magnesium-mediated arylation of amines via C-F bond activation of fluoroarenes." Chemical communications (Cambridge, England) vol. 55,30 (2019): 4339-4342. doi: https://doi.org/10.1039/c9cc01670h
Bole LJ, Davin L, Kennedy AR, McLellan R, Hevia E. Magnesium-mediated arylation of amines via C-F bond activation of fluoroarenes. Chem Commun (Camb). 2019 Apr 09;55(30):4339-4342. doi: 10.1039/c9cc01670h. PMID: 30911746.
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Chem Commun (Camb). 2019 Apr 09;55(30):4339-4342. doi: 10.1039/c9cc01670h.

Magnesium-mediated arylation of amines via C-F bond activation of fluoroarenes.

Chemical communications (Cambridge, England)

Leonie J Bole, Laia Davin, Alan R Kennedy, Ross McLellan, Eva Hevia

Affiliations

  1. WestCHEM, Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK. [email protected].

PMID: 30911746 DOI: 10.1039/c9cc01670h

Abstract

A series of new Mg(ii) amides featuring a bulky β-diketiminate backstop ligand, has been synthesised. These complexes are demonstrated to be excellent sources of nucleophilic amides that can participate in rapid C-F activation of several fluoroarenes at room temperature or using microwave assistance, leading to the installment of synthetically important C-N bonds via nucleophilic substitution.

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