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Phys Chem Chem Phys. 2019 Apr 21;21(15):7857-7866. doi: 10.1039/c9cp00216b. Epub 2019 Mar 27.

Difference between approximate and rigorously measured transference numbers in fluorinated electrolytes.

Physical chemistry chemical physics : PCCP

Deep B Shah, Hien Q Nguyen, Lorena S Grundy, Kevin R Olson, Sue J Mecham, Joseph M DeSimone, Nitash P Balsara

Affiliations

  1. Department of Chemical and Biomolecular Engineering, University of California, 201 Gilman Hall, Berkeley, CA 94720-1462, USA. [email protected].

PMID: 30916090 DOI: 10.1039/c9cp00216b

Abstract

The performance of binary electrolytes is governed by three transport properties: conductivity, salt diffusion coefficient, and transference number. Rigorous methods for measuring conductivity and the salt diffusion coefficient are well established and used routinely in the literature. The commonly used methods for measuring transference number are the steady-state current method, t

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