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Chem Commun (Camb). 2019 May 30;55(45):6357-6360. doi: 10.1039/c9cc02905b.

A multivalent mixed-metal strategy for single-Cu.

Chemical communications (Cambridge, England)

Jiaxu Zhang, Xiang Wang, Jing Lv, Dong-Sheng Li, Tao Wu

Affiliations

  1. College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China. [email protected].

PMID: 31065633 DOI: 10.1039/c9cc02905b

Abstract

Here we report two new metal-chalcogenide open frameworks (MCOFs) with large-sized supertetrahedral clusters bridged by an accessible single-cuprous ion via a multivalent mixed-metal strategy. Such Cu-rich semiconductor MCOFs have been investigated for the first time for nonenzymatic detection of glucose, and display good sensitivity and stability.

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